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Explain how the following substances would be classified under the Arrhenius and Brønsted–Lowry definitions of acids - HSC - SSCE Chemistry - Question 22 - 2023 - Paper 1

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Explain how the following substances would be classified under the Arrhenius and Brønsted–Lowry definitions of acids. Support your answer with relevant equations. •... show full transcript

Worked Solution & Example Answer:Explain how the following substances would be classified under the Arrhenius and Brønsted–Lowry definitions of acids - HSC - SSCE Chemistry - Question 22 - 2023 - Paper 1

Step 1

HCl(aq)

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Answer

According to Arrhenius, acids are substances that dissociate in water to produce hydrogen ions (H⁺). Therefore, HCl(aq) is classified as an Arrhenius acid since it ionizes in water to give H⁺ ions:

extHCl(aq)ightarrowextH+(aq)+extCl(aq) ext{HCl}(aq) ightarrow ext{H}^+(aq) + ext{Cl}^-(aq)

In the Brønsted–Lowry theory, acids are defined as proton donors. HCl(aq) donates a proton (H⁺) to water, further supporting its classification as an acid.

Step 2

NH₄Cl(aq)

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Answer

Ammonium chloride, NH₄Cl(aq), contains the ammonium ion (NH₄⁺), which can donate a proton in solution. In this case, it acts as a Brønsted–Lowry acid by providing an H⁺ ion to water, forming NH₃ and hydronium ions:

extNH4+(aq)+extH2O(l)ightarrowextNH3(aq)+extH3O+(aq) ext{NH}_4^+(aq) + ext{H}_2O(l) ightarrow ext{NH}_3(aq) + ext{H}_3O^+(aq)

Therefore, NH₄Cl(aq) is classified as a Brønsted–Lowry acid.

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