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A student has been asked to produce 185 mL of ethanol (MM = 46.068 g mol^-1) by fermenting glucose using yeast, as shown in the equation - HSC - SSCE Chemistry - Question 27 - 2023 - Paper 1

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A student has been asked to produce 185 mL of ethanol (MM = 46.068 g mol^-1) by fermenting glucose using yeast, as shown in the equation. C6H12O6(aq) → 2C2H5OH(aq) ... show full transcript

Worked Solution & Example Answer:A student has been asked to produce 185 mL of ethanol (MM = 46.068 g mol^-1) by fermenting glucose using yeast, as shown in the equation - HSC - SSCE Chemistry - Question 27 - 2023 - Paper 1

Step 1

Calculate the mass of ethanol required from density

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Answer

To find the mass of ethanol, we use the formula relating density, mass, and volume:

ho=mV ho = \frac{m}{V}

Rearranging this gives:

m=ρ×Vm = \rho \times V

Substituting the values:

m(ethanol)=0.789g mL1×185mL=146gm(ethanol) = 0.789 \, \text{g mL}^{-1} \times 185 \, \text{mL} = 146 \, \text{g}

Step 2

Calculate the number of moles of ethanol

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Answer

Using the molar mass:

n(ethanol)=mMM=146g46.068g mol1=3.17moln(ethanol) = \frac{m}{MM} = \frac{146 \, \text{g}}{46.068 \, \text{g mol}^{-1}} = 3.17 \, \text{mol}

Step 3

Calculate the volume of carbon dioxide produced

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Answer

From the reaction, 1 mole of glucose produces 2 moles of CO2. Therefore, 3.17 moles of ethanol would produce:

moles of CO2=2×n(ethanol)=2×3.17=6.34mol\text{moles of } CO_2 = 2 \times n(ethanol) = 2 \times 3.17 = 6.34 \, \text{mol}

Using the Ideal Gas Law to calculate the volume of CO2:

V=nRTPV = \frac{nRT}{P}

Where:

  • R = 8.314 J K^-1 mol^-1
  • T = 310 K
  • P = 100 kPa = 100,000 Pa

Substituting the values:

V=6.34mol×8.314JK1mol1×310extK100kPa=81.7extLV = \frac{6.34 \, \text{mol} \times 8.314 \, \text{JK}^{-1} \text{mol}^{-1} \times 310 \, ext{K}}{100 \, \text{kPa}} = 81.7 \, ext{L}

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