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A water sample contains at least one of the following anions at concentrations of 1.0 mol L⁻¹ - HSC - SSCE Chemistry - Question 30 - 2023 - Paper 1

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A water sample contains at least one of the following anions at concentrations of 1.0 mol L⁻¹. * bromide (Br⁻) * carbonate (CO₃²⁻) Outline a sequence of tests that... show full transcript

Worked Solution & Example Answer:A water sample contains at least one of the following anions at concentrations of 1.0 mol L⁻¹ - HSC - SSCE Chemistry - Question 30 - 2023 - Paper 1

Step 1

Add aqueous nitric acid – bubbles indicate carbonate present

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Answer

Adding excess nitric acid to the water sample will result in the formation of bubbles. This observation is an indication that carbonate ions (CO₃²⁻) are present because the acid reacts with the carbonate to produce carbon dioxide gas.

The reaction can be represented by the balanced chemical equation:

ightarrow ext{CO}_2(g) + ext{H}_2O(l)$$

Step 2

Add silver nitrate solution – creamy precipitate indicates bromide present

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Answer

After confirming the presence of carbonate, proceed by adding silver nitrate (AgNO₃) solution to the original water sample. If a creamy white precipitate forms, this indicates the presence of bromide ions (Br⁻).

The corresponding balanced chemical equation for this reaction is:

ightarrow ext{AgBr}(s)$$

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