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A household cleaning agent contains a weak base with the formula NaX - HSC - SSCE Chemistry - Question 18 - 2011 - Paper 1

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A household cleaning agent contains a weak base with the formula NaX. 1.00 g of this compound was dissolved in water to give 100.0 mL of solution. A 20.0 mL sample o... show full transcript

Worked Solution & Example Answer:A household cleaning agent contains a weak base with the formula NaX - HSC - SSCE Chemistry - Question 18 - 2011 - Paper 1

Step 1

Calculate the moles of hydrochloric acid used

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Answer

To find the moles of hydrochloric acid (HCl) used in the titration, we can use the formula:

Moles of HCl=Concentration (mol/L)×Volume (L)\text{Moles of HCl} = \text{Concentration (mol/L)} \times \text{Volume (L)}

We know the concentration of HCl is 0.100 mol/L, and the volume used is 24.4 mL (which is 0.0244 L):

Moles of HCl=0.100 mol/L×0.0244 L=0.00244 mol\text{Moles of HCl} = 0.100 \text{ mol/L} \times 0.0244 \text{ L} = 0.00244 \text{ mol}

Step 2

Determine the moles of the weak base present in the 20.0 mL sample

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Answer

From the reaction of the weak base (NaX) with hydrochloric acid, we assume it reacts in a 1:1 ratio. Therefore, the moles of the weak base in the 20.0 mL sample is also 0.00244 mol.

Step 3

Calculate the moles of the weak base in the total solution

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Answer

Since 20.0 mL is only a part of the 100.0 mL total solution, we need to find the total moles of the weak base dissolved in the entire solution:

Total moles of weak base=Moles in sample×100.0 mL20.0 mL=0.00244 mol×5=0.0122 mol\text{Total moles of weak base} = \text{Moles in sample} \times \frac{100.0 \text{ mL}}{20.0 \text{ mL}} = 0.00244 \text{ mol} \times 5 = 0.0122 \text{ mol}

Step 4

Calculate the molar mass of the weak base

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Answer

Now we can calculate the molar mass (M) of the weak base using the formula:

M=MassMolesM = \frac{\text{Mass}}{\text{Moles}}

We have a mass of 1.00 g of the weak base dissolved, which corresponds to 0.0122 mol:

M=1.00 g0.0122 mol82.0 g/molM = \frac{1.00 \text{ g}}{0.0122 \text{ mol}} \approx 82.0 \text{ g/mol}

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