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A gas is produced when 10.0 g of zinc is placed in 0.50 L of 0.20 mol L$^{-1}$ nitric acid - HSC - SSCE Chemistry - Question 26 - 2010 - Paper 1

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A gas is produced when 10.0 g of zinc is placed in 0.50 L of 0.20 mol L$^{-1}$ nitric acid. Calculate the volume of gas produced at 25°C and 100 kPa. Include a bala... show full transcript

Worked Solution & Example Answer:A gas is produced when 10.0 g of zinc is placed in 0.50 L of 0.20 mol L$^{-1}$ nitric acid - HSC - SSCE Chemistry - Question 26 - 2010 - Paper 1

Step 1

Balanced Chemical Equation

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Answer

The reaction between zinc and nitric acid can be represented by the following balanced chemical equation:

extZn(s)+2HNO3ext(aq)extZn(NO3ext)2ext(aq)+H2ext(g) ext{Zn (s) + 2 HNO}_3 ext{ (aq)} \rightarrow ext{Zn(NO}_3 ext{)}_2 ext{ (aq) + H}_2 ext{ (g)}

Step 2

Calculate Moles of Zinc

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To determine the number of moles of zinc present, we can use the formula:

extMoles=extmassextmolarmass ext{Moles} = \frac{ ext{mass}}{ ext{molar mass}}

The molar mass of zinc (Zn) is approximately 65.38 g/mol. Thus, the moles of zinc is:

extMolesofZn=10.0extg65.38extg/mol0.153extmol ext{Moles of Zn} = \frac{10.0 ext{ g}}{65.38 ext{ g/mol}} \approx 0.153 ext{ mol}

Step 3

Calculate Volume of Gas Produced

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According to the balanced chemical equation, 1 mole of zinc produces 1 mole of hydrogen gas. Therefore, the moles of hydrogen produced will also be approximately 0.153 mol.

Now, we can use the Ideal Gas Law to calculate the volume of gas produced at 25°C (298 K) and 100 kPa (0.1 MPa):

PV=nRTPV = nRT

Where:

  • P=100extkPa=0.1extMPaP = 100 ext{ kPa} = 0.1 ext{ MPa}
  • n=0.153extmoln = 0.153 ext{ mol}
  • R=8.314extJ/(molK)R = 8.314 ext{ J/(mol K)} or 0.08314extLkPa/(molK)0.08314 ext{ L kPa/(mol K)}
  • T=298extKT = 298 ext{ K}

Rearranging the equation to solve for volume (V):

v=nRTPv = \frac{nRT}{P}

Calculating the volume:

v=0.153extmol×0.08314extLkPa/(molK)×298extK0.1extMPa3.79extLv = \frac{0.153 ext{ mol} \times 0.08314 ext{ L kPa/(mol K)} \times 298 ext{ K}}{0.1 ext{ MPa}} \approx 3.79 ext{ L}

Thus, the volume of gas produced is approximately 3.79 L.

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