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Question 29
Consider this chemical equation. 2ClT(aq) + Br2(l) → 2BrT(aq) + Cl2(g) Will the reaction occur spontaneously? Justify your response.
Step 1
Answer
No, the reaction will not occur spontaneously. To assess spontaneity, we can refer to the standard electrode potentials for the half-reactions involved in the equation.
The half-reaction for chlorine is:
And for bromine:
Calculating the overall standard potential ( ) involves combining these half-reactions, leading to a total of:
The negative cell potential confirms that the reaction does not have a tendency to proceed in the forward direction spontaneously.
Step 2
Answer
Additionally, considering the positions of the elements on the periodic table, chlorine is generally more electronegative than bromine. Therefore, chlorine tends to gain electrons more favorably compared to bromine, suggesting that the reaction would not proceed spontaneously from left to right.
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