Photo AI

Consider this chemical equation - HSC - SSCE Chemistry - Question 29 - 2013 - Paper 1

Question icon

Question 29

Consider-this-chemical-equation-HSC-SSCE Chemistry-Question 29-2013-Paper 1.png

Consider this chemical equation. 2ClT(aq) + Br2(l) → 2BrT(aq) + Cl2(g) Will the reaction occur spontaneously? Justify your response.

Worked Solution & Example Answer:Consider this chemical equation - HSC - SSCE Chemistry - Question 29 - 2013 - Paper 1

Step 1

Determine if the reaction will occur spontaneously

96%

114 rated

Answer

No, the reaction will not occur spontaneously. To assess spontaneity, we can refer to the standard electrode potentials for the half-reactions involved in the equation.

The half-reaction for chlorine is:

Cl2(g)+2e2Cl(aq),E=1.36 VCl_2(g) + 2e^- \rightarrow 2Cl^-(aq), \quad E^\circ = -1.36 \text{ V}

And for bromine:

Br2(l)+2e2Br(aq),E=+1.08 VBr_2(l) + 2e^- \rightarrow 2Br^-(aq), \quad E^\circ = +1.08 \text{ V}

Calculating the overall standard potential ( EcellE^\circ_{cell} ) involves combining these half-reactions, leading to a total of:

Ecell=1.36+1.08=0.28 VE^\circ_{cell} = -1.36 + 1.08 = -0.28 \text{ V}

The negative cell potential confirms that the reaction does not have a tendency to proceed in the forward direction spontaneously.

Step 2

Justify your response using periodic table

99%

104 rated

Answer

Additionally, considering the positions of the elements on the periodic table, chlorine is generally more electronegative than bromine. Therefore, chlorine tends to gain electrons more favorably compared to bromine, suggesting that the reaction would not proceed spontaneously from left to right.

Join the SSCE students using SimpleStudy...

97% of Students

Report Improved Results

98% of Students

Recommend to friends

100,000+

Students Supported

1 Million+

Questions answered

;