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The diagram shows three reagent bottles containing acids - HSC - SSCE Chemistry - Question 24 - 2004 - Paper 1

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Question 24

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The diagram shows three reagent bottles containing acids. pH = 3.38 0.01 mol L⁻¹ Acetic acid pH = 2.56 0.01 mol L⁻¹ Citric acid pH = 2.00 0.01 mol L⁻¹ Hydrochl... show full transcript

Worked Solution & Example Answer:The diagram shows three reagent bottles containing acids - HSC - SSCE Chemistry - Question 24 - 2004 - Paper 1

Step 1

Calculate the pH after 10.0 mL of 0.01 mol L⁻¹ hydrochloric acid solution is diluted by the addition of 90.0 mL of distilled water.

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Answer

To calculate the new concentration of hydrochloric acid after dilution, use the dilution formula:

C1V1=C2V2C_1V_1 = C_2V_2

where:

  • C1=0.01extmolL1C_1 = 0.01 \, ext{mol L}^{-1} (initial concentration)
  • V1=10.0extmLV_1 = 10.0 \, ext{mL} (initial volume)
  • V2=10.0extmL+90.0extmL=100.0extmLV_2 = 10.0 \, ext{mL} + 90.0 \, ext{mL} = 100.0 \, ext{mL} (final volume)

Now, solving for C2C_2:

C2=C1V1V2=(0.01extmolL1)(10.0extmL)100.0extmL=0.001extmolL1C_2 = \frac{C_1V_1}{V_2} = \frac{(0.01 \, ext{mol L}^{-1})(10.0 \, ext{mL})}{100.0 \, ext{mL}} = 0.001 \, ext{mol L}^{-1}

Next, calculate the pH from the concentration of hydrochloric acid:

extpH=log[H+]=log(0.001)=3.00 ext{pH} = -\log[H^+] = -\log(0.001) = 3.00

Step 2

Explain the use of acetic acid and citric acid as food additives.

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Answer

Acetic acid and citric acid are commonly used as food additives for various reasons:

Acetic Acid

  • Preservative: Increases the acidity of foods, which helps to inhibit the growth of spoilage microbes.
  • Flavoring Agent: Adds a tangy flavor to foods, which enhances the overall taste and aroma.
  • pH Control: Helps to regulate pH in a variety of products, making them stable and safe for consumption.

Citric Acid

  • Natural Preservative: Effectively prevents oxidation, which can spoil food, thereby extending shelf life.
  • Flavor Enhancer: Provides a sour taste that can improve the flavor profile of various products like candies and beverages.
  • Antioxidant Properties: Helps to preserve color and quality in food products.

Step 3

Explain the difference in pH between the three acids in the diagram.

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Answer

The differences in pH among the three acids can be attributed to their relative strengths and dissociation in aqueous solutions:

Hydrochloric Acid

  • Strong Acid: Completely dissociates in water, leading to a low pH value (2.00).

Citric Acid

  • Weak Acid: Partially dissociates, resulting in a moderate pH value (2.56). Citric acid has multiple acidic protons, which affects its overall acidity.

Acetic Acid

  • Weaker Acid: Also partially dissociates but has a lower acidic strength compared to citric acid, leading to a higher pH value (3.38). The degree of dissociation is less than that of hydrochloric and citric acids, which reflects in its higher pH.

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