Which row of the table describes what happens when a solution of a weak acid is diluted? (Assume constant temperature.)
| K_a | Extent of acid ionisation |
|-------|--------------------------|
| A | Decreases | Increases |
| B | Decreases | Decreases |
| C | Remains the same | Increases |
| D | Remains the same | Decreases | - HSC - SSCE Chemistry - Question 6 - 2021 - Paper 1
Question 6
Which row of the table describes what happens when a solution of a weak acid is diluted? (Assume constant temperature.)
| K_a | Extent of acid ionisation |
|-----... show full transcript
Worked Solution & Example Answer:Which row of the table describes what happens when a solution of a weak acid is diluted? (Assume constant temperature.)
| K_a | Extent of acid ionisation |
|-------|--------------------------|
| A | Decreases | Increases |
| B | Decreases | Decreases |
| C | Remains the same | Increases |
| D | Remains the same | Decreases | - HSC - SSCE Chemistry - Question 6 - 2021 - Paper 1
Step 1
Which row of the table describes what happens when a solution of a weak acid is diluted?
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Answer
When a weak acid is diluted, the extent of ionisation generally increases. This is due to Le Chatelier's principle, which states that if a system at equilibrium is disturbed, the system will shift in a direction that counteracts that disturbance. Dilution reduces the concentration of the acid, which shifts the equilibrium to produce more ions. Thus, the dissociation constant Ka remains the same because it is determined by the nature of the acid and the temperature, but the extent of ionisation increases. Therefore, the correct answer is C: 'Remains the same' for Ka and 'Increases' for the extent of acid ionisation.