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An analytical chemist was using atomic absorption spectroscopy (AAS) to determine the manganese concentration in a sample - HSC - SSCE Chemistry - Question 4 - 2022 - Paper 1

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An analytical chemist was using atomic absorption spectroscopy (AAS) to determine the manganese concentration in a sample. The following diagram shows the absorbanc... show full transcript

Worked Solution & Example Answer:An analytical chemist was using atomic absorption spectroscopy (AAS) to determine the manganese concentration in a sample - HSC - SSCE Chemistry - Question 4 - 2022 - Paper 1

Step 1

Which lamp should be used to determine the manganese concentration in the sample?

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Answer

To determine the concentration of manganese using atomic absorption spectroscopy (AAS), we need to choose a lamp whose emission spectrum overlaps with the absorbance lines of manganese. From the provided absorbance diagram, the critical wavelengths for manganese absorption fall within a certain range.

Upon examining the emission spectra of the four lamps:

  • Lamp A: The emission does not match the desired wavelengths since it lacks the required peaks.
  • Lamp B: Similarly insufficient in matching the manganese absorption lines.
  • Lamp C: This lamp shows emission lines that coincide perfectly with the absorbance peaks of manganese, making it suitable for the analysis.
  • Lamp D: Does not provide the necessary spectral overlap required for effective absorption measurement.

Thus, the lamp that should be used to determine the manganese concentration in the sample is Lamp C.

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