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A solution prepared by stirring Na2O(s) in water undergoes an acid-base reaction with a solution prepared from SO2(g) and water - VCE - SSCE Chemistry - Question 4 - 2007 - Paper 1

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A solution prepared by stirring Na2O(s) in water undergoes an acid-base reaction with a solution prepared from SO2(g) and water. Which one of the following salts cou... show full transcript

Worked Solution & Example Answer:A solution prepared by stirring Na2O(s) in water undergoes an acid-base reaction with a solution prepared from SO2(g) and water - VCE - SSCE Chemistry - Question 4 - 2007 - Paper 1

Step 1

Determine the Reaction Products

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Answer

When Na2O(s) is added to water, it reacts to form sodium hydroxide (NaOH), a strong base.

Furthermore, the reaction of SO2(g) with water produces sulfurous acid (H2SO3).

The acid-base reaction can be represented as: extNaOH+extH2SO3NaHSO3+H2O ext{NaOH} + ext{H2SO3} \rightarrow \text{NaHSO3} + \text{H2O}

This shows that sodium hydrogen sulfite (NaHSO3) is created in the reaction.

Step 2

Evaluate Possible Salts

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Answer

Given the products of the reaction, we need to determine which salt could be isolated:

  • Na2S: Not produced in the reaction.
  • NaHSO3: This is formed directly in the reaction.
  • Na2SO3: Not formed; it would require a different stoichiometry.
  • Na2SO4: This requires the presence of sulfuric acid, which is not formed here.

Thus, only NaHSO3 is correct.

Step 3

Conclusion

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Answer

The only salt that can be isolated as a product of the acid-base reaction is NaHSO3.

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