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A 10 mL sample of 0.010 M HCl is diluted by adding distilled water at constant temperature - VCE - SSCE Chemistry - Question 8 - 2010 - Paper 1

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A 10 mL sample of 0.010 M HCl is diluted by adding distilled water at constant temperature. Which one of the following items correctly shows the effect of the diluti... show full transcript

Worked Solution & Example Answer:A 10 mL sample of 0.010 M HCl is diluted by adding distilled water at constant temperature - VCE - SSCE Chemistry - Question 8 - 2010 - Paper 1

Step 1

Which one of the following items correctly shows the effect of the dilution on the concentrations of H⁺ and OH⁻ ions in the solution?

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Answer

When a strong acid like HCl is diluted with water, the concentration of H⁺ ions decreases because the same number of H⁺ ions is now distributed in a larger volume. According to the ion-product constant of water, which is at 25°C, we have:

Kw=[H+][OH]=1.0imes1014K_w = [H^+][OH^-] = 1.0 imes 10^{-14}

As the concentration of H⁺ ions decreases, the concentration of OH⁻ ions must increase to keep the product constant at 25°C. Therefore, the correct response is:

Thus, the answer is B:

  • decrease
  • increase.

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