One of the steps involved in the industrial preparation of sulfuric acid is the oxidation of sulfur dioxide to sulfur trioxide according to the equation
$$2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)$$
a - VCE - SSCE Chemistry - Question 8 - 2006 - Paper 1
Question 8
One of the steps involved in the industrial preparation of sulfuric acid is the oxidation of sulfur dioxide to sulfur trioxide according to the equation
$$2SO_2(g) ... show full transcript
Worked Solution & Example Answer:One of the steps involved in the industrial preparation of sulfuric acid is the oxidation of sulfur dioxide to sulfur trioxide according to the equation
$$2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)$$
a - VCE - SSCE Chemistry - Question 8 - 2006 - Paper 1
Step 1
a. Give the name or formula for the catalyst that is most widely used for this reaction.
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Answer
The catalyst most widely used for the oxidation of sulfur dioxide to sulfur trioxide is vanadium(V) oxide, often denoted as ( V_2O_5 ).
Step 2
b. Why?
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Answer
The reaction is actually performed at a higher temperature of approximately 450°C in industry to enhance the reaction rate. At elevated temperatures, the reaction proceeds faster, allowing for a higher throughput of sulfur trioxide production. Although the conversion percentage is lower at higher temperatures, the rate of reaction is significantly increased, making the process more feasible for industrial use.
Step 3
c. i. Explain why high pressures would increase the equilibrium yield of sulfur trioxide in this reaction.
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Answer
Increasing the pressure will shift the equilibrium towards the side with fewer moles of gas, according to Le Chatelier's principle. In this reaction, there are 2 moles of gas on the left (reactants) and 2 moles on the right (products). While the number of moles remains the same, the reaction can still favor the production of sulfur trioxide at higher pressures, due to increased collisions between molecules.
Step 4
c. ii. Explain why atmospheric pressure is usually used in industry, even though high pressures increase the equilibrium yield of sulfur trioxide in this reaction.
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Atmospheric pressure is often used in industry due to the economic and safety considerations associated with high-pressure systems. Operating under high pressures can be costly and requires robust equipment to ensure safety and integrity. Thus, the balance between yield and operational efficiency is often achieved by working at atmospheric pressure.
Step 5
d. i. Write a balanced chemical equation for dilute sulfuric acid added to sodium carbonate solution.
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