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If Solution X has a pH of 3 and Solution Y has a pH of 6, we can conclude that A - VCE - SSCE Chemistry - Question 4 - 2014 - Paper 1

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If Solution X has a pH of 3 and Solution Y has a pH of 6, we can conclude that A. [$H^+$] in Solution X is 1000 times that of [$H^+$] in Solution Y. B. [$H^+$] in So... show full transcript

Worked Solution & Example Answer:If Solution X has a pH of 3 and Solution Y has a pH of 6, we can conclude that A - VCE - SSCE Chemistry - Question 4 - 2014 - Paper 1

Step 1

A. [$H^+$] in Solution X is 1000 times that of [$H^+$] in Solution Y.

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Answer

To determine the concentration of hydrogen ions [H+H^+], we use the formula:

[$H^+] = 10^{-pH}

For Solution X (pH = 3): [$H^+]_X = 10^{-3} ext{ mol/L}

For Solution Y (pH = 6): [$H^+]_Y = 10^{-6} ext{ mol/L}

Calculating the ratio:

\frac{[$H^+]_X}{[$H^+]_Y} = \frac{10^{-3}}{10^{-6}} = 10^{3} = 1000

Thus, this statement is true.

Step 2

B. [$H^+$] in Solution X is half that of [$H^+] in Solution Y.

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Answer

From the previous calculation, we know:

[$H^+]_X = 10^{-3} ext{ mol/L} [$H^+]_Y = 10^{-6} ext{ mol/L}

To check if [H+H^+] in Solution X is half that of Solution Y:

[$H^+]_X \neq \frac{1}{2}[$H^+]_Y

Thus, this statement is false.

Step 3

C. [$OH^-$] in Solution Y is twice that of [$OH^-$] in Solution X.

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Answer

To find the [OHOH^-] concentration, we use the relationship:

[$OH^-] = \frac{K_w}{[$H^+]}

Where KwK_w (ion-product constant of water) at 25°C is approximately 1.0×10141.0 \times 10^{-14}.

For Solution X:

[$OH^-]_X = \frac{10^{-14}}{10^{-3}} = 10^{-11} ext{ mol/L}

For Solution Y:

[$OH^-]_Y = \frac{10^{-14}}{10^{-6}} = 10^{-8} ext{ mol/L}

Calculating the ratio:

\frac{[$OH^-]_Y}{[$OH^-]_X} = \frac{10^{-8}}{10^{-11}} = 10^{3} = 1000

Thus, this statement is false.

Step 4

D. Solution Y must contain a stronger acid than Solution X.

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Answer

Since we have established that Solution X has a higher concentration of [H+H^+] compared to Solution Y, this indicates that Solution X is indeed more acidic. Therefore, this statement is false.

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