a. By referring to their electron configurations, explain why metals in the first transition series of the periodic table typically have several different oxidation states while Group II metals have only one - VCE - SSCE Chemistry - Question 6 - 2004 - Paper 1
Question 6
a. By referring to their electron configurations, explain why metals in the first transition series of the periodic table typically have several different oxidation ... show full transcript
Worked Solution & Example Answer:a. By referring to their electron configurations, explain why metals in the first transition series of the periodic table typically have several different oxidation states while Group II metals have only one - VCE - SSCE Chemistry - Question 6 - 2004 - Paper 1
Step 1
By referring to their electron configurations, explain why metals in the first transition series of the periodic table typically have several different oxidation states while Group II metals have only one.
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Answer
The transition metals have d-orbitals that allow for the loss of various numbers of electrons from both the 4s and 3d subshells. This results in multiple oxidation states due to the ability to lose electrons from different energy levels. In contrast, Group II metals only lose their two outermost s electrons, leading to a single oxidation state.
Step 2
Predict the trend in the following properties of the second period elements, moving from lithium to fluorine, giving an explanation in support of each prediction.
Property: Atomic size
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Answer
Atomic size decreases as we move from lithium to fluorine because of the increasing effective nuclear charge due to the addition of protons. This stronger attraction pulls outer electrons closer to the nucleus.
Step 3
Predict the trend in the following properties of the second period elements, moving from lithium to fluorine, giving an explanation in support of each prediction.
Property: Electronegativity
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Answer
Electronegativity increases from lithium to fluorine as the nuclear charge increases, which enhances the attraction of the nucleus for bonding electrons, making the elements more electronegative.