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The expression for the equilibrium constant for the reverse reaction is A - VCE - SSCE Chemistry - Question 1 - 2014 - Paper 1

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The expression for the equilibrium constant for the reverse reaction is A. $K = \frac{[H_2O][CH_4]}{[H_2]^2[CO_2]}$ B. $K = \frac{[H_2]^1[CO_2]}{[H_2O]^2[CH_4]}$ ... show full transcript

Worked Solution & Example Answer:The expression for the equilibrium constant for the reverse reaction is A - VCE - SSCE Chemistry - Question 1 - 2014 - Paper 1

Step 1

Determine the Expression for the Equilibrium Constant

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Answer

To find the equilibrium constant expression for the reverse reaction, we first need to know the forward reaction. For a general reaction of the form:

aA+bBcC+dDaA + bB \rightleftharpoons cC + dD

the expression for the equilibrium constant (K) for the forward reaction is given by:

Kforward=[C]c[D]d[A]a[B]bK_{forward} = \frac{[C]^c[D]^d}{[A]^a[B]^b}

The equilibrium constant for the reverse reaction (K_reverse) is the inverse of the forward reaction:

Kreverse=1Kforward=[A]a[B]b[C]c[D]dK_{reverse} = \frac{1}{K_{forward}} = \frac{[A]^a[B]^b}{[C]^c[D]^d}

Assuming the forward reaction is:

2H2+CO22H2O+CH42H_2 + CO_2 \rightleftharpoons 2H_2O + CH_4

the equilibrium constant expression can be written as:

Kforward=[H2O]2[CH4][H2]2[CO2]K_{forward} = \frac{[H_2O]^2[CH_4]}{[H_2]^2[CO_2]}

Consequently, the expression for the reverse reaction would be:

Kreverse=[H2]2[CO2][H2O]2[CH4]K_{reverse} = \frac{[H_2]^2[CO_2]}{[H_2O]^2[CH_4]}

Hence, the correct choice is:

B. K=[H2]1[CO2][H2O]2[CH4]K = \frac{[H_2]^1[CO_2]}{[H_2O]^2[CH_4]}

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