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The concentration profile below represents a change to the above equilibrium system at time $t_1$: The following concentrations are represented: - $[Fe(SCN)]^{2+}$ - $[Fe^{3+}]$ - $[SCN^-]$ Which one of the following would account for the changes in concentration at time $t_1$? A - VCE - SSCE Chemistry - Question 7 - 2012 - Paper 1

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The-concentration-profile-below-represents-a-change-to-the-above-equilibrium-system-at-time-$t_1$:--The-following-concentrations-are-represented:----$[Fe(SCN)]^{2+}$----$[Fe^{3+}]$---$[SCN^-]$--Which-one-of-the-following-would-account-for-the-changes-in-concentration-at-time-$t_1$?--A-VCE-SSCE Chemistry-Question 7-2012-Paper 1.png

The concentration profile below represents a change to the above equilibrium system at time $t_1$: The following concentrations are represented: - $[Fe(SCN)]^{2+}$... show full transcript

Worked Solution & Example Answer:The concentration profile below represents a change to the above equilibrium system at time $t_1$: The following concentrations are represented: - $[Fe(SCN)]^{2+}$ - $[Fe^{3+}]$ - $[SCN^-]$ Which one of the following would account for the changes in concentration at time $t_1$? A - VCE - SSCE Chemistry - Question 7 - 2012 - Paper 1

Step 1

A. the addition of SCN^-

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The addition of SCN^- increases the concentration of thiocyanate ions in the system. According to Le Chatelier's Principle, this will shift the equilibrium to the right, forming more of the complex ion [Fe(SCN)]2+[Fe(SCN)]^{2+} while decreasing the concentration of Fe3+Fe^{3+} as it reacts with the added SCNSCN^-. This explains the observed changes in concentration at time t1t_1.

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