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Consider the following TLC plate of compounds X, Y and Z developed using a suitable mobile phase on a polar stationary phase - VCE - SSCE Chemistry - Question 6 - 2010 - Paper 1

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Consider the following TLC plate of compounds X, Y and Z developed using a suitable mobile phase on a polar stationary phase. The Rf value of the most polar compone... show full transcript

Worked Solution & Example Answer:Consider the following TLC plate of compounds X, Y and Z developed using a suitable mobile phase on a polar stationary phase - VCE - SSCE Chemistry - Question 6 - 2010 - Paper 1

Step 1

Identify the Most Polar Component

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Answer

In Thin Layer Chromatography (TLC), the most polar component will have the least Rf value. This occurs because polar substances tend to interact more with the stationary phase (in this case, a polar stationary phase) and, therefore, travel less distance up the plate.

Step 2

Determine the Rf Value from the TLC Plate

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Answer

From the given TLC plate, we observe that compound X is the closest to the origin, indicating it is the most polar. To find the Rf value, we can use the formula:

Rf=distancetravelledbycompounddistancetravelledbysolventRf = \frac{distance\:travelled\:by\:compound}{distance\:travelled\:by\:solvent}

Looking at the scale, we can estimate that the distance travelled by compound X is approximately 0.29 cm, while the distance travelled by the solvent front is approximately 3.20 cm. Thus:

Rf=0.293.200.09Rf = \frac{0.29}{3.20} \approx 0.09

Since X is the most polar component, we can conclude it has the lowest Rf value.

Step 3

Select the Correct Answer

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Answer

Based on the Rf values we deduced, the value closest to our calculation from the options provided is A. 0.29. Hence, this is the answer.

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