The industrial production of sulfuric acid can be described as a four-stage process beginning with the burning of raw sulfur with oxygen - VCE - SSCE Chemistry - Question 5 - 2004 - Paper 1
Question 5
The industrial production of sulfuric acid can be described as a four-stage process beginning with the burning of raw sulfur with oxygen.
Stage 1 The burning of sul... show full transcript
Worked Solution & Example Answer:The industrial production of sulfuric acid can be described as a four-stage process beginning with the burning of raw sulfur with oxygen - VCE - SSCE Chemistry - Question 5 - 2004 - Paper 1
Step 1
Stage 1 The burning of sulfur
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Answer
The combustion of sulfur in oxygen can be represented by the following chemical equation:
S(s)+O2(g)→SO2(g)
In this reaction, sulfur (S) reacts with oxygen (O₂) to produce sulfur dioxide (SO₂).
Step 2
Stage 2 The oxidation of sulfur from the +4 to the +6 oxidation state
Give the equation for this reaction.
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Answer
The oxidation of sulfur from the +4 to the +6 oxidation state can be described by the following reaction:
2SO2(g)+O2(g)→2SO3(g)
In this reaction, sulfur dioxide (SO₂) is oxidized to sulfur trioxide (SO₃).
Step 3
What goes wrong in the industrial process if the temperature for this stage of the process is too high, and why?
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If the temperature is too high during the oxidation of sulfur, it can lead to a decrease in the yield of sulfur trioxide (SO₃). This is because the forward reaction is exothermic; thus, increasing the temperature shifts the equilibrium position to favor the reactants. In essence, if the temperature is elevated too much, the production of SO₃ becomes less efficient, resulting in lower yields.