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A chemical reaction has a ΔH of −150 kJ mol⁻¹ and the activation energy for its reverse reaction is 350 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 8 - 2007 - Paper 1

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A chemical reaction has a ΔH of −150 kJ mol⁻¹ and the activation energy for its reverse reaction is 350 kJ mol⁻¹. The activation energy, in kJ mol⁻¹, of the forward ... show full transcript

Worked Solution & Example Answer:A chemical reaction has a ΔH of −150 kJ mol⁻¹ and the activation energy for its reverse reaction is 350 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 8 - 2007 - Paper 1

Step 1

The activation energy of the forward reaction is determined from the given data.

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Answer

To find the activation energy ( E_a) of the forward reaction, we can use the relationship between the activation energies of the forward and reverse reactions as well as the enthalpy change ( ΔH). This relationship is given by the equation: Ea,extforward=Ea,extreverse+riangleHE_{a, ext{forward}} = E_{a, ext{reverse}} + riangle H

Given that:

ΔH = −150 kJ mol⁻¹ (for the forward reaction)

E_{a, ext{reverse}} = 350 kJ mol⁻¹

Substituting these values into the equation:

Ea,extforward=350extkJmol1+(150extkJmol1)E_{a, ext{forward}} = 350 ext{ kJ mol}^{-1} + (-150 ext{ kJ mol}^{-1}) Ea,extforward=350150E_{a, ext{forward}} = 350 - 150 Ea,extforward=200extkJmol1E_{a, ext{forward}} = 200 ext{ kJ mol}^{-1}

Thus, the activation energy of the forward reaction is +200 kJ mol⁻¹, which corresponds to option B.

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