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In a particular chlorination reaction, a single hydrogen atom of 2,2-dimethylbutane, C6H14, is replaced by one chlorine atom - VCE - SSCE Chemistry - Question 12 - 2009 - Paper 1

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In a particular chlorination reaction, a single hydrogen atom of 2,2-dimethylbutane, C6H14, is replaced by one chlorine atom. More than one compound of formula C6H13... show full transcript

Worked Solution & Example Answer:In a particular chlorination reaction, a single hydrogen atom of 2,2-dimethylbutane, C6H14, is replaced by one chlorine atom - VCE - SSCE Chemistry - Question 12 - 2009 - Paper 1

Step 1

Identify the structure of 2,2-dimethylbutane

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Answer

2,2-dimethylbutane is a branched alkane with the formula C6H14. It has two methyl groups attached to the second carbon of the butane backbone.

Step 2

Analyze possible positions for chlorination

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Answer

In the chlorination reaction, chlorine can replace a hydrogen atom on any carbon atom. Given the symmetrical nature of 2,2-dimethylbutane, we need to consider unique products resulting from chlorination.

Step 3

Count unique products

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Answer

When considering chlorination:

  1. Replacing a hydrogen from one of the terminal CH3 groups gives one unique product (C6H13Cl).
  2. Replacing a hydrogen from the central carbon (C2) also results in a unique product due to the identical environments of the hydrogen atoms. Thus, the total number of unique chlorinated products is 4.

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