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In order to help prevent tooth decay, fluoride ions at a level of 0.9 mg L^{-1} of F^{-} are added to Melbourne’s public water supplies - VCE - SSCE Chemistry - Question 4 - 2004 - Paper 1

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In order to help prevent tooth decay, fluoride ions at a level of 0.9 mg L^{-1} of F^{-} are added to Melbourne’s public water supplies. The fluoride ions are obtain... show full transcript

Worked Solution & Example Answer:In order to help prevent tooth decay, fluoride ions at a level of 0.9 mg L^{-1} of F^{-} are added to Melbourne’s public water supplies - VCE - SSCE Chemistry - Question 4 - 2004 - Paper 1

Step 1

Calculate the mass of sodium fluoride in mg that must be present in one litre of water to produce a concentration of fluoride ions of 0.90 mg L^{-1}.

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Answer

To find the mass of sodium fluoride (NaF) required to achieve a fluoride ion concentration of 0.90 mg L^{-1}, we can use the molar mass of NaF.

The molar mass of NaF is approximately 42.0 g/mol.

  1. Since 0.9 mg of fluoride ions corresponds to:

    extMassofF=0.90extmg=0.90imes103extg ext{Mass of F}^{-} = 0.90 ext{ mg} = 0.90 imes 10^{-3} ext{ g}

  2. Next, calculate the moles of fluoride ions:

    n = rac{ ext{mass}}{ ext{molar mass}} = rac{0.90 imes 10^{-3}}{19.0} ext{ mol}

  3. Then, calculate the total mass of sodium fluoride required:

    ext{mass of NaF} = n imes ext{molar mass of NaF} = rac{0.90 imes 10^{-3}}{19.0} imes 42.0 ext{ g} = 2.0 ext{ mg}

Thus, the mass of sodium fluoride needed in one litre is 2.0 mg.

Step 2

What mass of sodium fluoride, in kilogram, must be added to a 750 ML reservoir (1 ML = 10^{-6} L) to produce a concentration of fluoride ions of 0.90 mg L^{-1}?

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Answer

To calculate the mass of sodium fluoride for a 750 mL reservoir, follow these steps:

  1. First, convert 750 mL to litres:

    750extmL=750imes103extL=0.750extL750 ext{ mL} = 750 imes 10^{-3} ext{ L} = 0.750 ext{ L}

  2. Calculate the total amount of fluoride ions needed for 0.750 L:

    extmassofF=extconcentrationimesextvolume=0.90extmgL1imes0.750extL=0.675extmg ext{mass of F}^{-} = ext{concentration} imes ext{volume} = 0.90 ext{ mg L}^{-1} imes 0.750 ext{ L} = 0.675 ext{ mg}

  3. Next, convert mg to kg:

    0.675extmg=0.675imes103extg=1.5imes106extkg0.675 ext{ mg} = 0.675 imes 10^{-3} ext{ g} = 1.5 imes 10^{-6} ext{ kg}

  4. Calculate the mass of NaF:

    ext{mass of NaF} = rac{0.675 imes 10^{-3} ext{ g}}{19.0} imes 42.0

    The total mass needed is approximately 1.5 x 10^{-3} kg.

Step 3

Calculate the number of fluoride ions swallowed by a person who drank one litre of water from the reservoir.

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Answer

To find the number of fluoride ions in 1 litre of water:

  1. Calculate the mass of fluoride in 1 L using the previous concentration:

    extmassofF=0.90extmgL1imes1extL=0.90extmg=0.90imes103extg ext{mass of F}^{-} = 0.90 ext{ mg L}^{-1} imes 1 ext{ L} = 0.90 ext{ mg} = 0.90 imes 10^{-3} ext{ g}

  2. Determine moles of fluoride ions:

    n = rac{ ext{mass}}{ ext{molar mass}} = rac{0.90 imes 10^{-3}}{19.0} ext{ mol}

  3. Convert moles to number of ions:

    Use Avogadro's number (NAext=6.022imes1023extmol1N_A ext{ = } 6.022 imes 10^{23} ext{ mol}^{-1}) to determine:

    extNumberofions=nimesNA ext{Number of ions} = n imes N_A

    This results in approximately 2.91 imes 10^{19} fluoride ions in one litre.

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