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A small electric vehicle is powered by rechargeable lead-acid car batteries - VCE - SSCE Chemistry - Question 4 - 2004 - Paper 1

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A small electric vehicle is powered by rechargeable lead-acid car batteries. The energy that drives the vehicle comes from the cell reaction $$\text{Pb(s)} + \text{... show full transcript

Worked Solution & Example Answer:A small electric vehicle is powered by rechargeable lead-acid car batteries - VCE - SSCE Chemistry - Question 4 - 2004 - Paper 1

Step 1

Write the equation for the cathode half reaction.

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Answer

PbO2(s)+2H+(aq)+2ePbSO4(s)+H2O(l)\text{PbO}_2(s) + 2\text{H}^+(aq) + 2e^- \rightarrow \text{PbSO}_4(s) + \text{H}_2\text{O}(l)

Step 2

How much energy, in kJ, is used by the vehicle in travelling for 2.5 hours?

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Answer

To calculate the energy used, we use the formula:

Energy=Power×Time\text{Energy} = \text{Power} \times \text{Time}

Given that the power consumption is 1.0 kJ/s and the travelling time is 2.5 hours, we first convert the time into seconds:

2.5 hours=2.5×3600=9000 seconds2.5 \text{ hours} = 2.5 \times 3600 = 9000 \text{ seconds}

Now, substituting the values:

Energy=1.0 kJ/s×9000 s=9000 kJ\text{Energy} = 1.0 \text{ kJ/s} \times 9000 \text{ s} = 9000 \text{ kJ}

Step 3

Write the equation for the overall chemical reaction that occurs when the battery is being recharged.

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Answer

2PbSO4(s)+2H2O(l)Pb(s)+PbO2(s)+2H2SO4(aq)2\text{PbSO}_4(s) + 2\text{H}_2\text{O}(l) \rightarrow \text{Pb(s)} + \text{PbO}_2(s) + 2\text{H}_2\text{SO}_4(aq)

Step 4

What voltage should be used to recharge each battery?

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Answer

The voltage required to recharge the battery must be greater than 12 V, so a voltage of at least 12.1 V should be applied to ensure effective recharging.

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