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This question is about some elements in Group 7 and their compounds - AQA - A-Level Chemistry - Question 6 - 2022 - Paper 1

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This question is about some elements in Group 7 and their compounds. Chlorine is added to some drinking water supplies to decrease the risk of people suffering from... show full transcript

Worked Solution & Example Answer:This question is about some elements in Group 7 and their compounds - AQA - A-Level Chemistry - Question 6 - 2022 - Paper 1

Step 1

State why the amount of chlorine added must be controlled.

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Answer

The amount of chlorine added must be controlled because excessive chlorine can be toxic and pose health risks, such as respiratory issues or skin irritation, as well as causing unpleasant tastes and odors in drinking water.

Step 2

Give an equation for the reaction of chlorine with water to form a solution containing two acids.

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Answer

The equation for the reaction is:

Cl2+H2O→HCl+HClOCl_2 + H_2O \rightarrow HCl + HClO

Step 3

Explain, with reference to electrons, why this is a redox reaction.

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Answer

This is a redox (reduction-oxidation) reaction as chlorine undergoes reduction and oxidation simultaneously. In this reaction, one chlorine atom gains electrons to form chloride ions (Cl-) while the other loses electrons to form hypochlorous acid (HClO), showing a transfer of electrons.

Step 4

State the observation the student would make.

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Answer

The student would observe a brown solution or black solid forming, indicating the displacement reaction.

Step 5

Give an ionic equation for the reaction.

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Answer

The ionic equation for the reaction between chlorine and sodium iodide is:

Cl2+2I−→2Cl−+I2Cl_2 + 2I^- \rightarrow 2Cl^- + I_2

Step 6

Give an equation for the formation of these sulfur-containing products.

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Answer

The equations for the formation of sulfur-containing products when sodium iodide reacts with sulfuric acid are:

  1. H2SO4+2NaI→Na2SO4+I2+H2OH_2SO_4 + 2NaI \rightarrow Na_2SO_4 + I_2 + H_2O
  2. H2SO4+2NaI→Na2SO4+SO2+2HIH_2SO_4 + 2NaI \rightarrow Na_2SO_4 + SO_2 + 2 HI

Step 7

State the role of sulfuric acid in the formation of these products.

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Answer

In this reaction, sulfuric acid acts as an oxidizing agent, facilitating the oxidation of iodide ions (I-) to iodine (I2) or sulfur dioxide (SO2).

Step 8

Deduce the identity of the sodium halide.

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Answer

The identity of the sodium halide is sodium iodide (NaI).

Step 9

Suggest the identity of the gas.

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Answer

The identity of the gas is chlorine (Cl2).

Step 10

Give an ionic equation for the formation of this gas from the impurity.

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Answer

The ionic equation for the formation of chlorine gas from sodium iodide is:

2NaI+Cl2→2Na++2Cl−+I22NaI + Cl_2 \rightarrow 2Na^+ + 2Cl^- + I_2

Step 11

Use your understanding of the electron pair repulsion theory to draw the shape of this ion.

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Answer

The shape of the ClF2- ion is linear with two bonded pairs and three lone pairs on the central chlorine atom.

Step 12

Explain why the ion has the shape you have drawn.

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Answer

The ClF2- ion has a linear shape due to the presence of three lone pairs of electrons that repel each other and the two bonded pairs of electrons, resulting in a geometry that minimizes repulsion.

Step 13

Suggest a value for the bond angle in the ion.

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Answer

The bond angle in the ClF2- ion is approximately 180 degrees.

Step 14

Give an equation for this reaction.

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Answer

The equation for the extraction of titanium from titanium(IV) chloride is:

TiCl4+2Mg→Ti+2MgCl2TiCl_4 + 2Mg \rightarrow Ti + 2MgCl_2

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