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This question is about sodium halides - AQA - A-Level Chemistry - Question 9 - 2020 - Paper 1

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This question is about sodium halides. 1. State what is observed when silver nitrate solution is added to sodium fluoride solution. 2. State one observation when s... show full transcript

Worked Solution & Example Answer:This question is about sodium halides - AQA - A-Level Chemistry - Question 9 - 2020 - Paper 1

Step 1

State what is observed when silver nitrate solution is added to sodium fluoride solution.

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Answer

The solution remains colourless, indicating no precipitate formation.

Step 2

State one observation when solid sodium chloride reacts with concentrated sulfuric acid.

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Answer

The reaction produces steamy or white fumes of hydrogen chloride gas.

Step 3

Give an equation for the reaction.

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Answer

The equation for the reaction is: 2NaCl+H2SO4→Na2SO4+HCl↑2NaCl + H_2SO_4 \rightarrow Na_2SO_4 + HCl \uparrow

Step 4

State the role of the chloride ions in the reaction.

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Answer

Chloride ions act as a base or proton acceptor during the reaction.

Step 5

Give an equation for the redox reaction between solid sodium bromide and concentrated sulfuric acid.

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Answer

The equation for the redox reaction is: 2NaBr+2H2SO4→Na2SO4+Br2+SO2+2H2O2NaBr + 2H_2SO_4 \rightarrow \\ Na_2SO_4 + Br_2 + SO_2 + 2H_2O

Step 6

Explain, using oxidation states, why this is a redox reaction.

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Answer

In the reaction, bromide ions (Br−^{-}) change oxidation state from -1 to 0 when forming bromine (Br2_2), and sulfur changes oxidation state from +6 (in H2_2SO4_4) to +4 (in SO2_2). Thus, Br is oxidized and H2_2SO4_4 is reduced, indicating a redox reaction.

Step 7

State what is observed when aqueous chlorine is added to sodium bromide solution.

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Answer

A yellow or orange solution is observed due to the formation of bromine.

Step 8

Give an ionic equation for the reaction.

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Answer

The ionic equation for the reaction is: Cl2+2Br−→2Cl−+Br2Cl_2 + 2Br^- \rightarrow 2Cl^- + Br_2

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