You are provided with samples of each of the four compounds - AQA - A-Level Chemistry - Question 7 - 2017 - Paper 2
Question 7
You are provided with samples of each of the four compounds.
K: H3C–C(COOH)–C(Br)–C(OH)–H
L: H3C–C(COOH)–C(CH3)–C(OH)–H
M: H3C–C(COOH)–C(COOH)–C(OH)–H
N: H3C... show full transcript
Worked Solution & Example Answer:You are provided with samples of each of the four compounds - AQA - A-Level Chemistry - Question 7 - 2017 - Paper 2
Step 1
Test with NaHCO₃ / pH Indicator
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Answer
Perform a test with sodium bicarbonate (NaHCO₃) and a pH indicator.
Compounds K and M will react and produce effervescence due to the release of carbon dioxide (
CO₂) from the carboxylic acid group (–COOH). This reaction indicates the presence of the carboxylic acid functional group.
Observe pH changes where K and M may turn the indicator color.
L and N will show no reaction.
Step 2
Test with Fehling's / Tollens'
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Conduct tests with Fehling's solution or Tollens' reagent.
Compound N, containing aldehyde groups, will react positively showing a color change (red precipitate in Fehling's).
K, L and M which have ketone or alcohol groups may show a weak or no reaction.
The distinct positive reaction indicates the presence of the aldehyde functional group in N.
Step 3
Test with Acids (H₂SO₄)
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Finally, treat the samples with sulfuric acid (H₂SO₄).
Observations may vary: K and M could show ester formation while L containing a branched structure, may not form visible products.
N will show no ester formation, confirming the alcohol functionality.