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Which pair of reagents does not produce ethanol? A - AQA - A-Level Chemistry - Question 31 - 2022 - Paper 3

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Which pair of reagents does not produce ethanol? A. CH$_3$CH$._2$Br and NaOH(aq) B. CH$_3$COOCH$_2$ and NaOH(aq) C. HCOOCH$_2$CH$._3$ and NaOH(aq) D. CH$_3$CHO a... show full transcript

Worked Solution & Example Answer:Which pair of reagents does not produce ethanol? A - AQA - A-Level Chemistry - Question 31 - 2022 - Paper 3

Step 1

Identify the Reagents

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Answer

We have four pairs of reagents, as follows:

  • A: CH3_3CH2_2Br and NaOH(aq)
  • B: CH3_3COOCH2_2 and NaOH(aq)
  • C: HCOOCH2_2CH3_3 and NaOH(aq)
  • D: CH3_3CHO and NaBH4_4(aq)

Step 2

Analyze Each Option

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Answer

We need to determine which pair does not result in the production of ethanol:

  • Option A: CH3_3CH2_2Br reacts with NaOH(aq) to form ethanol through nucleophilic substitution.
  • Option B: CH3_3COOCH2_2 (an ester) reacts with NaOH(aq), undergoing hydrolysis, which can produce ethanol.
  • Option C: HCOOCH2_2CH3_3 reacts similarly with NaOH(aq) to yield ethanol through hydrolysis.
  • Option D: CH3_3CHO (acetaldehyde) reacts with NaBH4_4(aq), but it does not produce ethanol directly.

Step 3

Conclusion

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Answer

The pair that does not produce ethanol is B: CH3_3COOCH2_2 and NaOH(aq).

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