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The E\u00b0 values for two electrodes are shown - AQA - A-Level Chemistry - Question 13 - 2019 - Paper 3

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The E\u00b0 values for two electrodes are shown. Fe<sup>3+</sup>(aq) + 2e<sup>-</sup> \u2192 Fe(s) E\u00b0 = -0.44 V Cu<sup>2+</sup>(aq) + 2e<sup>-</sup> \u2192 Cu... show full transcript

Worked Solution & Example Answer:The E\u00b0 values for two electrodes are shown - AQA - A-Level Chemistry - Question 13 - 2019 - Paper 3

Step 1

Calculate the EMF of the cell

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Answer

To find the EMF of the cell, we use the formula:

Ecell=EcathodeEanodeE_{cell} = E_{cathode} - E_{anode}

In this case:

  • The cathode is the copper half-cell (Cu²⁺/Cu) with a standard reduction potential of +0.34 V.
  • The anode is the iron half-cell (Fe³⁺/Fe) with a standard reduction potential of -0.44 V.

Substituting the values into the equation:

Ecell=0.34V(0.44V)E_{cell} = 0.34 V - (-0.44 V)

This simplifies to:

Ecell=0.34V+0.44V=0.78VE_{cell} = 0.34 V + 0.44 V = 0.78 V

Therefore, the EMF of the cell is +0.78 V.

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