Some bond enthalpies are given - AQA - A-Level Chemistry - Question 10 - 2020 - Paper 3
Question 10
Some bond enthalpies are given.
| Bond | C–H | O–H | O=O | C=O |
|---------------|-----|-----|-----|-----|
| Bond enthalpy / kJ mol⁻¹ | 412 | 463 | 496 | 7... show full transcript
Worked Solution & Example Answer:Some bond enthalpies are given - AQA - A-Level Chemistry - Question 10 - 2020 - Paper 3
Step 1
Calculate bond enthalpy for reactants
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Answer
To find the total bond enthalpy for the reactants, we need to consider the bonds broken in the reactants. For one molecule of CH₄, there are 4 C–H bonds, and for 2 molecules of O₂, there are 2 O=O bonds:
extTotalbondenthalpyforreactants=4×412kJ+2×496kJ
Calculating this gives:
=1648+992=2640kJ
Step 2
Calculate bond enthalpy for products
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Answer
Next, we calculate the total bond enthalpy for the products. For 1 molecule of CO₂, there are 2 C=O bonds, and for 2 molecules of H₂O, there are 4 O–H bonds:
extTotalbondenthalpyforproducts=2×743kJ+4×463kJ
Calculating this gives:
=1486+1852=3338kJ
Step 3
Find the enthalpy change
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Answer
The enthalpy change (\Delta H) for the reaction can be found using the formula:
ΔH=Total bond enthalpy for products−Total bond enthalpy for reactants
Substituting in the values gives:
ΔH=3338−2640=698kJ
Since the value is positive, the reaction is endothermic. Thus, the answer is option D: -698 kJ.