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This question is about the reactions of alkanes - AQA - A-Level Chemistry - Question 1 - 2018 - Paper 2

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This question is about the reactions of alkanes. Alkanes can be used as fuels. Give an equation for the combustion of heptane (C7H16) in an excess of oxygen. Hept... show full transcript

Worked Solution & Example Answer:This question is about the reactions of alkanes - AQA - A-Level Chemistry - Question 1 - 2018 - Paper 2

Step 1

Give an equation for the combustion of heptane (C7H16) in an excess of oxygen.

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Answer

The balanced equation for the complete combustion of heptane in excess oxygen is:

C7H16+11O27CO2+8H2OC_7H_{16} + 11 O_2 \rightarrow 7 CO_2 + 8 H_2O

Step 2

Identify a suitable catalyst for this process.

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Answer

A suitable catalyst for the catalytic cracking of hexadecane is zeolite or aluminosilicate.

Step 3

Give one condition other than high temperature.

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Answer

One condition for the process is to operate under slight to moderate pressure.

Step 4

Give an equation for the catalytic cracking of one molecule of hexadecane to produce one molecule of heptane, one molecule of cyclohexane and one other product.

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Answer

The equation for the catalytic cracking of hexadecane can be represented as:

C16H34C7H16+C6H12+C3H6C_{16}H_{34} \rightarrow C_7H_{16} + C_6H_{12} + C_3H_6

Step 5

Give equations for the propagation steps in the reaction of butane to form 2-chlorobutane.

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Answer

The propagation steps involved can be illustrated as follows:

  1. C4H10+Cl2C4H9Cl+HClC_4H_{10} + Cl_2 \rightarrow C_4H_9Cl + HCl
  2. C4H9Cl+Cl2C4H8Cl2+HClC_4H_9Cl + Cl_2 \rightarrow C_4H_8Cl_2 + HCl

Step 6

Identify the radical produced from this CFC that is responsible for the depletion of ozone in the atmosphere.

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Answer

The radical produced from the CFC (chlorofluorocarbon) that is responsible for ozone depletion is Cl· (Chlorine radical).

Step 7

Explain, with the aid of equations, why a single radical can cause the decomposition of many molecules of ozone.

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Answer

The chlorine radical can propagate the reaction that destroys ozone. The reaction sequence is as follows:

  1. The chlorine radical reacts with ozone: Cl+O3ClO+O2Cl· + O_3 \rightarrow ClO· + O_2
  2. The chlorine monoxide radical can react with another ozone molecule: ClO+OCl+O2ClO· + O \rightarrow Cl· + O_2

This shows that one chlorine radical can lead to the depletion of multiple ozone molecules through a chain reaction.

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