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Calculate the pH of a 0.150 mol dm⁻³ solution of ethanoic acid at 25 °C - AQA - A-Level Chemistry - Question 4 - 2022 - Paper 1

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Calculate the pH of a 0.150 mol dm⁻³ solution of ethanoic acid at 25 °C. Give your answer to 2 decimal places. For ethanoic acid, Kₐ = 1.74 × 10⁻⁵ mol dm⁻³ at 25 °C... show full transcript

Worked Solution & Example Answer:Calculate the pH of a 0.150 mol dm⁻³ solution of ethanoic acid at 25 °C - AQA - A-Level Chemistry - Question 4 - 2022 - Paper 1

Step 1

Calculate the concentration of [H⁺]

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Answer

Using the expression for the dissociation of ethanoic acid:

Ka=[H+][CH3COO][CH3COOH]K_a = \frac{[H^+][CH_3COO^-]}{[CH_3COOH]}

Assuming that the dissociation is small, we can approximate:

[CH3COOH]0.150[CH_3COOH] \approx 0.150

Let ([H^+] = x), then the expression becomes:

Ka=x20.150xx20.150K_a = \frac{x^2}{0.150 - x} \approx \frac{x^2}{0.150}

Therefore, we get:

x2=1.74×105×0.150x^2 = 1.74 \times 10^{-5} \times 0.150

Calculating gives:

x22.61×106x^2 \approx 2.61 \times 10^{-6}

Taking the square root, we find:

[H+]1.61×103[H^+] \approx 1.61 \times 10^{-3}.

Step 2

Calculate pH

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Answer

Now, we can calculate the pH as follows:

pH=log[H+]pH = -\log{[H^+]}

Substituting in the value:

pH=log(1.61×103)2.79pH = -\log{(1.61 \times 10^{-3})} \approx 2.79.

Thus, the final answer rounded to two decimal places is:

pH=2.79pH = 2.79.

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