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This question is about some Group 7 compounds - AQA - A-Level Chemistry - Question 5 - 2019 - Paper 1

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This question is about some Group 7 compounds. Solid sodium chloride reacts with concentrated sulfuric acid. Give an equation for this reaction. State the role of ... show full transcript

Worked Solution & Example Answer:This question is about some Group 7 compounds - AQA - A-Level Chemistry - Question 5 - 2019 - Paper 1

Step 1

Give an equation for this reaction.

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Answer

The reaction between solid sodium chloride (NaCl) and concentrated sulfuric acid (H₂SO₄) can be represented by the following equation:

NaCl+H2SO4NaHSO4+HClNaCl + H_2SO_4 \rightarrow NaHSO_4 + HCl

Step 2

State the role of the sulfuric acid in this reaction.

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Answer

The role of sulfuric acid in this reaction is as a proton donor. It donates a proton to the chloride ion, facilitating the formation of hydrogen chloride gas.

Step 3

Give an equation.

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Answer

When sodium bromide (NaBr) reacts with concentrated sulfuric acid, the equation is as follows:

NaBr+H2SO4NaHSO4+HBrNaBr + H_2SO_4 \rightarrow NaHSO_4 + HBr

Step 4

Give one other observation.

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Answer

One observable change during this reaction is the production of brown fumes, which is indicative of the formation of sulfur dioxide (SO₂).

Step 5

State the role of the sulfuric acid.

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Answer

In this reaction, sulfuric acid acts as an oxidizing agent, allowing the bromide ion to be oxidized to bromine.

Step 6

Give the oxidation state of chlorine in NaClO, and in NaCl.

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Answer

In NaClO, the oxidation state of chlorine is +1. In NaCl, the oxidation state of chlorine is -1.

Step 7

State, in terms of redox, what happens to chlorine in the reaction 05.3.

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Answer

In the reaction, chlorine is both oxidized and reduced, participating in a disproportionation reaction.

Step 8

Give the formulas of D, E and F.

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Answer

The formulas are:
D = AgBr
E = AgCl
F = Ag(NH₃)₂Cl

Step 9

Give an ionic equation to show the formation of E.

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Answer

The ionic equation for the formation of silver chloride (AgCl) from silver ions (Ag⁺) and chloride ions (Cl⁻) is:

Ag+(aq)+Cl(aq)AgCl(s)Ag^+ (aq) + Cl^- (aq) \rightarrow AgCl (s)

Step 10

Give an equation to show the conversion of D into G.

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Answer

The conversion of D (AgBr) into G can be represented by the following reaction:

2AgBr+2NH3+H2O2Ag(NH3)2Br+HBr2AgBr + 2NH_3 + H_2O \rightarrow 2Ag(NH_3)_2Br + HBr

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