Coconut oil contains a triester with three identical R groups - AQA - A-Level Chemistry - Question 1 - 2021 - Paper 2
Question 1
Coconut oil contains a triester with three identical R groups. This triester reacts with potassium hydroxide.
$$\text{RCOO}^- \text{CH}_2 + 3\text{KOH} \rightarrow ... show full transcript
Worked Solution & Example Answer:Coconut oil contains a triester with three identical R groups - AQA - A-Level Chemistry - Question 1 - 2021 - Paper 2
Step 1
Complete the equation by drawing the structure of the other product of this reaction in the box.
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Answer
The structure of the other product formed by the reaction of a triester with potassium hydroxide is the corresponding alcohol. For this reaction, the structure would be:
CH2(OH)(CH2)n. The complete equation now shows the production of potassium carboxylate salts and glycerol (the alcohol).
Step 2
Name the type of compound shown by the formula RCOOK
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Answer
The type of compound shown by the formula RCOOK is a potassium carboxylate salt or simply a carboxylate salt. One use for carboxylate salts includes their function as surfactants in soaps and detergents.
Step 3
Deduce the value of n in CH_n(CH_2)_n.
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Answer
Given that the molecular mass M = 638.0, we first subtract the mass of the carboxylate fragments: 638 - 173 = 465 g/mol. The aliphatic chain contributes 14n to the molecular mass, thus we solve for n:
465=14n
Substituting gives:
n = \frac{465}{14} = 33.21428571
Since n must be an integer, round down to 33.
Step 4
Calculate the percentage by mass of the triester (M=638) in the coconut oil.
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First, we determine the amount of HCl reacted:
Amount of HCl=CHCl×VHCl=0.100 mol dm−3×15.65 cm3×10001=0.0015655 mol
The remaining KOH:
\text{Moles of KOH initially} = \frac{0.421}{56.1} \approx 0.00749 \text{ mol}
\text{Moles of KOH after reaction} = 0.00749 - 0.0015655 = 0.0059245
The amount of triester = moles of KOH that reacted×3M = (0.0015655)∗3638
Now, we calculate the percentage:
Percentage=(1.450mass of triester)×100
The final percentage should be calculated as required.
Step 5
Suggest why aqueous ethanol is a suitable solvent when heating the coconut oil with KOH.
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Answer
Aqueous ethanol acts as a suitable solvent because it dissolves both the coconut oil (triester) and KOH, thus facilitating the hydrolysis reaction between them efficiently.
Step 6
Give a safety precaution used when heating the mixture.
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A proper safety precaution is to wear safety goggles.
Justification: This ensures that if any solution splashes or spills during heating, it does not harm the eyes.