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Coconut oil contains a triester with three identical R groups - AQA - A-Level Chemistry - Question 1 - 2021 - Paper 2

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Coconut oil contains a triester with three identical R groups. This triester reacts with potassium hydroxide. $$\text{RCOO}^- \text{CH}_2 + 3\text{KOH} \rightarrow ... show full transcript

Worked Solution & Example Answer:Coconut oil contains a triester with three identical R groups - AQA - A-Level Chemistry - Question 1 - 2021 - Paper 2

Step 1

Complete the equation by drawing the structure of the other product of this reaction in the box.

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Answer

The structure of the other product formed by the reaction of a triester with potassium hydroxide is the corresponding alcohol. For this reaction, the structure would be: CH2(OH)(CH2)n\text{CH}_2\text{(OH)}\text{(CH}_2\text{)}_n. The complete equation now shows the production of potassium carboxylate salts and glycerol (the alcohol).

Step 2

Name the type of compound shown by the formula RCOOK

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Answer

The type of compound shown by the formula RCOOK is a potassium carboxylate salt or simply a carboxylate salt. One use for carboxylate salts includes their function as surfactants in soaps and detergents.

Step 3

Deduce the value of n in CH_n(CH_2)_n.

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Answer

Given that the molecular mass M = 638.0, we first subtract the mass of the carboxylate fragments: 638 - 173 = 465 g/mol. The aliphatic chain contributes 14n14n to the molecular mass, thus we solve for n: 465=14n465 = 14n Substituting gives: n = \frac{465}{14} = 33.21428571
Since n must be an integer, round down to 33.

Step 4

Calculate the percentage by mass of the triester (M=638) in the coconut oil.

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First, we determine the amount of HCl reacted: Amount of HCl=CHCl×VHCl=0.100 mol dm3×15.65 cm3×11000=0.0015655 mol\text{Amount of HCl} = C_{HCl} \times V_{HCl} = 0.100 \text{ mol dm}^{-3} \times 15.65 \text{ cm}^3 \times \frac{1}{1000} = 0.0015655 \text{ mol} The remaining KOH: \text{Moles of KOH initially} = \frac{0.421}{56.1} \approx 0.00749 \text{ mol} \text{Moles of KOH after reaction} = 0.00749 - 0.0015655 = 0.0059245
The amount of triester = moles of KOH that reacted×M3\text{moles of KOH that reacted} \times \frac{M}{3} = (0.0015655)6383(0.0015655) * \frac{638}{3}
Now, we calculate the percentage: Percentage=(mass of triester1.450)×100\text{Percentage} = \left( \frac{\text{mass of triester}}{1.450} \right) \times 100 The final percentage should be calculated as required.

Step 5

Suggest why aqueous ethanol is a suitable solvent when heating the coconut oil with KOH.

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Answer

Aqueous ethanol acts as a suitable solvent because it dissolves both the coconut oil (triester) and KOH, thus facilitating the hydrolysis reaction between them efficiently.

Step 6

Give a safety precaution used when heating the mixture.

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Answer

A proper safety precaution is to wear safety goggles.

Justification: This ensures that if any solution splashes or spills during heating, it does not harm the eyes.

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