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Solution A contains the compound [Cu(H2O)6]Cl2 - AQA - A-Level Chemistry - Question 7 - 2017 - Paper 1

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Solution A contains the compound [Cu(H2O)6]Cl2. 1. State the type of bonding between the oxygen and hydrogen in this compound. 2. State why the chloride ions in th... show full transcript

Worked Solution & Example Answer:Solution A contains the compound [Cu(H2O)6]Cl2 - AQA - A-Level Chemistry - Question 7 - 2017 - Paper 1

Step 1

State the type of bonding between the oxygen and hydrogen in this compound.

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Answer

The type of bonding between the oxygen and hydrogen in the compound [Cu(H2O)6]Cl2 is covalent.

Step 2

State why the chloride ions in this compound are not considered to be ligands.

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Answer

The chloride ions are not considered to be ligands because they do not donate a lone pair or form a coordinate (dative) bond to the copper ion.

Step 3

Write an ionic equation for the reaction that occurs when solution A is converted into solution B and state the colour of solution B.

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Answer

Equation:

[Cu(H2O)6]^{2+} + 4NH3 \rightarrow [Cu(NH3)4]^{2+} + 6H2O

Colour:

Deep blue.

Step 4

Identify the blue-green solid C.

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Answer

The blue-green solid C is CuCO3, or copper carbonate.

Step 5

Identify reagent D and write an ionic equation for the reaction that occurs when the yellow-green solution is formed from solution A.

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Answer

Identify reagent D:

HCl (hydrochloric acid)

Equation:

[Cu(H2O)6]^{2+} + 4Cl^- \rightarrow [CuCl4]^{2-} + 6H2O

Step 6

Explain why colorimetry cannot be used to determine the concentration of solutions containing [CuCl2].

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Answer

Colorimetry cannot be used to determine the concentration of solutions containing [CuCl2] because it is colorless and cannot absorb frequencies of visible light; therefore, it does not produce a measurable color change.

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