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In which conversion is the metal reduced? A Cr₂O₇²⁻ → CrO₄²⁻ B MnO₄²⁻ → MnO₄⁻ C TiO₂ → TiO₂²⁻ D VO₃⁻ → VO⁺ - AQA - A-Level Chemistry - Question 11 - 2020 - Paper 3

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Question 11

In-which-conversion-is-the-metal-reduced?--A-Cr₂O₇²⁻-→-CrO₄²⁻-B-MnO₄²⁻-→-MnO₄⁻-C-TiO₂-→-TiO₂²⁻-D-VO₃⁻-→-VO⁺-AQA-A-Level Chemistry-Question 11-2020-Paper 3.png

In which conversion is the metal reduced? A Cr₂O₇²⁻ → CrO₄²⁻ B MnO₄²⁻ → MnO₄⁻ C TiO₂ → TiO₂²⁻ D VO₃⁻ → VO⁺

Worked Solution & Example Answer:In which conversion is the metal reduced? A Cr₂O₇²⁻ → CrO₄²⁻ B MnO₄²⁻ → MnO₄⁻ C TiO₂ → TiO₂²⁻ D VO₃⁻ → VO⁺ - AQA - A-Level Chemistry - Question 11 - 2020 - Paper 3

Step 1

A Cr₂O₇²⁻ → CrO₄²⁻

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Answer

In this conversion, chromium goes from a +6 oxidation state in Cr₂O₇²⁻ to a +6 oxidation state in CrO₄²⁻. Therefore, there is no reduction.

Step 2

B MnO₄²⁻ → MnO₄⁻

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Answer

Here, manganese remains in the +7 oxidation state on both sides, indicating no reduction takes place.

Step 3

C TiO₂ → TiO₂²⁻

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Answer

Titanium in TiO₂ is in the +4 oxidation state and remains so, so again no reduction occurs.

Step 4

D VO₃⁻ → VO⁺

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Answer

In this conversion, vanadium is reduced from a +5 oxidation state in VO₃⁻ to a +4 oxidation state in VO⁺. This confirms that the metal is reduced in this reaction.

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