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Sodium and sulfur react together to form sodium sulfide, Na2S - CIE - A-Level Chemistry - Question 12 - 2019 - Paper 1

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Sodium and sulfur react together to form sodium sulfide, Na2S. How do the atomic radius and ionic radius of sodium compare with those of sulfur? A atomic radius io... show full transcript

Worked Solution & Example Answer:Sodium and sulfur react together to form sodium sulfide, Na2S - CIE - A-Level Chemistry - Question 12 - 2019 - Paper 1

Step 1

atomic radius

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Answer

The atomic radius of sodium is smaller than that of sulfur. This is because as you move across a period from left to right in the periodic table, the atomic radius decreases due to increasing positive charge in the nucleus that draws the electrons closer.

Step 2

ionic radius

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Answer

For the ionic radius, sodium forms a cation (Na⁺), which has a smaller radius than its atomic radius due to the loss of an electron. In contrast, sulfur forms an anion (S²⁻), which has a larger radius than its atomic radius because of the addition of electrons. Therefore, compare the ionic radii: sodium is less than sulfur.

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