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River water in a chalky agricultural area contains Ca<sup>2+</sup>, Mg<sup>2+</sup>, CO<sub>3</sub><sup>2-</sup>, HCO<sub>3</sub><sup>-</sup>, Cl<sup>-</sup> and NO<sub>3</sub><sup>-</sup> ions - CIE - A-Level Chemistry - Question 18 - 2016 - Paper 1

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Question 18

River-water-in-a-chalky-agricultural-area-contains-Ca<sup>2+</sup>,-Mg<sup>2+</sup>,-CO<sub>3</sub><sup>2-</sup>,-HCO<sub>3</sub><sup>-</sup>,-Cl<sup>-</sup>-and-NO<sub>3</sub><sup>-</sup>-ions-CIE-A-Level Chemistry-Question 18-2016-Paper 1.png

River water in a chalky agricultural area contains Ca<sup>2+</sup>, Mg<sup>2+</sup>, CO<sub>3</sub><sup>2-</sup>, HCO<sub>3</sub><sup>-</sup>, Cl<sup>-</sup> and NO<... show full transcript

Worked Solution & Example Answer:River water in a chalky agricultural area contains Ca<sup>2+</sup>, Mg<sup>2+</sup>, CO<sub>3</sub><sup>2-</sup>, HCO<sub>3</sub><sup>-</sup>, Cl<sup>-</sup> and NO<sub>3</sub><sup>-</sup> ions - CIE - A-Level Chemistry - Question 18 - 2016 - Paper 1

Step 1

What will be precipitated from the river water following the addition of calcium hydroxide?

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Answer

When calcium hydroxide (Ca(OH)₂) is added to the river water, it will react with the carbonate ions (CO₃²⁻) present in the water. This leads to the formation of calcium carbonate (CaCO₃), which is a poorly soluble salt and will precipitate out of the solution.

The reaction can be summarized as follows:

ightarrow ext{CaCO}_3 (s) + 2 ext{OH}^-$$ Therefore, the precipitate formed is calcium carbonate (CaCO₃), corresponding to option B.

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