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3 Crude oil is a mixture of hydrocarbons and provides many useful chemicals when processed - CIE - A-Level Chemistry - Question 3 - 2016 - Paper 1

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3 Crude oil is a mixture of hydrocarbons and provides many useful chemicals when processed. Two of the stages involved in the processing of crude oil are fractiona... show full transcript

Worked Solution & Example Answer:3 Crude oil is a mixture of hydrocarbons and provides many useful chemicals when processed - CIE - A-Level Chemistry - Question 3 - 2016 - Paper 1

Step 1

What has to be done to the crude oil before it enters the column?

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Answer

The crude oil must be heated to a high temperature to ensure it vaporizes and enters the fractional distillation column in a gaseous state.

Step 2

What trend in structure is there from fraction A to fraction F?

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Answer

From fraction A to fraction F, there is an increasing molecular size, which corresponds to a higher number of carbon atoms per molecule, leading to longer carbon chains.

Step 3

State the trends in two properties of the fractions from A to F.

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Answer

  1. Viscosity: It increases with higher fractions, as larger molecules are more viscous.
  2. Flammability: It decreases from fractions A to F, with lighter fractions being more flammable due to simpler structures.

Step 4

Write an equation for the cracking of C_nH_{2n} to form the products ethene and one other hydrocarbon in a 2:1 mole ratio.

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Answer

The equation for the cracking process can be represented as:
CnH2n→C2H4+C(n−2)H(2(n−1))C_nH_{2n} \rightarrow C_2H_4 + C_{(n-2)}H_{(2(n-1))}

Step 5

Suggest a use for each of the products from your equation in (i). Explain what makes each product from (i) suitable for the use you suggest.

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Answer

  1. Use of ethene: Ethene is widely used in the production of plastics such as polyethylene. Its unsaturated nature allows it to undergo polymerization easily.
    Explanation: The double bond in ethene is reactive and facilitates the formation of long polymer chains.

  2. Use of the other hydrocarbon: Depending on the specific hydrocarbon, it could be used as a fuel or a solvent.
    Explanation: Many hydrocarbons from cracking are effective fuels due to their combustion properties.

Step 6

Explain how and why oxides of nitrogen are produced in internal combustion engines.

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Answer

Oxides of nitrogen are produced in internal combustion engines due to the high temperature and pressure conditions. Under these conditions, nitrogen and oxygen react to form nitrogen oxides (NO and NO2). This reaction is facilitated by the heat generated during combustion.

Step 7

Write an equation for the reaction between nitrogen monoxide and carbon monoxide in a catalytic converter.

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Answer

The reaction can be represented as:
2NO+2CO→2N2+2CO22NO + 2CO \rightarrow 2N_2 + 2CO_2

Step 8

Write equations to show the involvement of nitrogen monoxide in the formation of acid rain from atmospheric sulfur dioxide.

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Answer

  1. 2NO+O2→2NO22NO + O_2 \rightarrow 2NO_2
  2. SO2+NO2+H2O→H2SO4SO_2 + NO_2 + H_2O \rightarrow H_2SO_4

Step 9

Describe two of the problems associated with acid rain.

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Answer

  1. Harm to aquatic life: Acid rain can lower the pH of water bodies, adversely affecting fish and other aquatic organisms.
  2. Damage to vegetation: It can lead to the leaching of nutrients from soil and damage leaves, rendering plants weaker and less productive.

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