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You are to determine the enthalpy change for the reaction of hydrated sodium carbonate, Na2CO3.xH2O, with hydrochloric acid, HCl(aq) - CIE - A-Level Chemistry - Question 2 - 2011 - Paper 1

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You are to determine the enthalpy change for the reaction of hydrated sodium carbonate, Na2CO3.xH2O, with hydrochloric acid, HCl(aq). The equation for this reaction... show full transcript

Worked Solution & Example Answer:You are to determine the enthalpy change for the reaction of hydrated sodium carbonate, Na2CO3.xH2O, with hydrochloric acid, HCl(aq) - CIE - A-Level Chemistry - Question 2 - 2011 - Paper 1

Step 1

Method

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Answer

  1. Support the Plastic Cup: Place the plastic cup inside a 250 cm³ beaker to provide stability during the experiment.

  2. Measure the Hydrochloric Acid: Use a measuring cylinder to accurately transfer 25 cm³ of hydrochloric acid (FB 4) into the plastic cup.

  3. Tilt the Beaker: Carefully tilt the beaker so that the bulb of the thermometer is immersed in the solution to obtain a precise temperature reading.

  4. Measure Initial Temperature: Measure and record the initial temperature of the hydrochloric acid solution before adding the sodium carbonate.

  5. Weigh the Sodium Carbonate: Measure and record the mass of the tube containing the hydrated sodium carbonate (FB 3).

  6. Add Sodium Carbonate: Carefully tip all the weighed hydrated sodium carbonate into the plastic cup containing hydrochloric acid. This will initiate the reaction.

  7. Observe Effervescence: Be aware that effervescence will occur due to the release of gas (CO2). Add the sodium carbonate in small portions while constantly stirring with the thermometer to ensure thorough mixing.

  8. Record Temperature after Reaction: After adding the sodium carbonate, record the highest temperature of the solution reached during the reaction.

  9. Reweigh the Tube: After the reaction, reweigh the tube to determine any residual amount of sodium carbonate left unreacted (FB 3).

  10. Document Data: In the provided space, record both balance readings, both temperature measurements, the mass of sodium carbonate used, and the decrease in temperature of the solution.

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