This is about electrolysis - AQA - GCSE Chemistry Combined Science - Question 1 - 2018 - Paper 1
Question 1
This is about electrolysis.
A student investigates the mass of copper produced during electrolysis of copper chloride solution.
Figure 1 shows the apparatus.
Which... show full transcript
Worked Solution & Example Answer:This is about electrolysis - AQA - GCSE Chemistry Combined Science - Question 1 - 2018 - Paper 1
Step 1
Which gas is produced at the positive electrode (anode)?
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Answer
The gas produced at the positive electrode (anode) is chlorine. This is because during the electrolysis of copper chloride solution, chlorine is released at the anode as a result of chloride ions being oxidized.
Step 2
Copper is produced at the negative electrode (cathode). What does this tell you about the reactivity of copper?
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Copper is less reactive than hydrogen. This indicates that copper can be reduced at the cathode, while hydrogen is produced at a lower reactivity.
Step 3
Determine the mean mass of copper produced after 3 minutes.
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To find the mean mass of copper produced after 3 minutes, we can use the values from Table 1:
Mean mass = ( \frac{2.40 + 2.41 + 2.39}{3} = 2.40 , \text{mg} )
Step 4
Calculate the mass X of copper produced in Experiment 2 after 5 minutes.
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From Table 1, to find the mass X after 5 minutes, we have:
Mass after 5 minutes for Experiment 1: 3.02 mg
Mass after 5 minutes for Experiment 3: 3.01 mg
Mean mass for 5 minutes = ( \frac{3.02 + 3.01 + X}{3} )
Setting equal to the mean (as we see that Experiment 2 is in the range of the others), we can approximate:
Mean = 3.06 mg thus, X is calculated to yield approximately 3.06 mg.
Step 5
Calculate the mass of solid copper chloride used in each experiment.
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Answer
We know that the copper chloride solution contained 300 grams per dm³. The student used 50 cm³ of this solution in each experiment. Therefore:
Mass of CuCl₂ in 50 cm³ = ( 300 , \text{g/dm}^3 \times \frac{50}{1000} , \text{dm}^3 = 15 , \text{g} )
Thus, the mass of solid copper chloride used in each experiment is 15 g.