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This question is about oxygen - AQA - GCSE Chemistry Combined Science - Question 3 - 2019 - Paper 1

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This question is about oxygen. Hydrogen reacts with oxygen. 2 H₂ (g) + O₂ (g) → 2 H₂O (g) Figure 2 shows the relative energies of the reactants and products at a c... show full transcript

Worked Solution & Example Answer:This question is about oxygen - AQA - GCSE Chemistry Combined Science - Question 3 - 2019 - Paper 1

Step 1

Label the activation energy on Figure 2

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Answer

To label the activation energy on Figure 2, draw a line from the reactants (2H₂ + O₂) to the top of the curve (the peak). The activation energy is the energy required to reach this peak from the reactants, which is between 800 kJ and 2160 kJ.

Step 2

Determine the overall energy change for the reaction between hydrogen and oxygen shown in Question 03.1

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Answer

From Figure 2, the energy of the reactants (2H₂ + O₂) is 800 kJ while the energy of the products (2H₂O) is 300 kJ. The overall energy change can be calculated as follows:

the energy change = energy of products - energy of reactants

Thus, the energy change = 300 kJ - 800 kJ = -500 kJ.

Step 3

Draw the electrons in the outer energy levels in Figure 3

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Answer

In Figure 3, draw the outer energy levels of the two oxygen atoms in O₂. Each oxygen atom has 6 electrons in its outer shell. Show these as two overlapping circles, each with 6 dots representing the outer electrons and 2 shared pairs indicated by pairs of dots or a line to show the bonding between them.

Step 4

Calculate the overall energy change for the reaction.

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Answer

To calculate the overall energy change for the decomposition of hydrogen peroxide, we need to consider the bond energies:

  1. Bonds Broken:

    • 2(O-H) at 463 kJ each = 2 × 463 = 926 kJ
    • 1(O-O) at 138 kJ = 138 kJ
    • Total energy for bonds broken = 926 + 138 = 1064 kJ
  2. Bonds Made:

    • 4(O-H) at 463 kJ each = 4 × 463 = 1852 kJ
    • 1(O=O) at 496 kJ = 496 kJ
    • Total energy for bonds made = 1852 + 496 = 2348 kJ
  3. Energy Change:

    Energy change = Bonds broken - Bonds made Energy change = 1064 - 2348 = -1284 kJ The overall energy change for the reaction is -284 kJ.

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