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This question is about zinc and magnesium - AQA - GCSE Chemistry - Question 4 - 2014 - Paper 1

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This question is about zinc and magnesium. Zinc is produced by electrolysis of molten zinc chloride, as shown in Figure 4. Figure 4 Negative electrode Positiv... show full transcript

Worked Solution & Example Answer:This question is about zinc and magnesium - AQA - GCSE Chemistry - Question 4 - 2014 - Paper 1

Step 1

Why must the zinc chloride be molten for electrolysis?

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Answer

The zinc chloride must be molten for electrolysis so that the charged particles can move freely. In a solid state, the ions are fixed in place and unable to carry charge, thus hindering the conduction of electricity.

Step 2

Describe what happens at the negative electrode.

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Answer

At the negative electrode, zinc ions gain electrons, which is referred to as reduction. The reaction can be summarized as follows:

  1. Zinc ions (Zn²⁺) move towards the negative electrode.
  2. Electrons from the electrode are taken up by the zinc ions, converting them to neutral zinc atoms.
  3. Consequently, metallic zinc is formed at the negative electrode.

Step 3

Complete the half equation for the reaction at the positive electrode.

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The half equation for the reaction at the positive electrode is:

ightarrow Cl_2 + 2 e^-$$

Step 4

How can you tell from the equation that the reaction is done at a high temperature?

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The reaction is typically at a high temperature because magnesium, which is a gas in this reaction, is produced. This indicates that the substances must reach a temperature high enough to move from solid to gas form, which is only feasible at elevated temperatures.

Step 5

What is meant by an endothermic reaction?

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An endothermic reaction is one that takes in more energy from its surroundings than it releases. In other words, it requires heat to proceed, leading to a decrease in the temperature of the surroundings.

Step 6

Calculate the mass of magnesium oxide needed to produce 1.2 tonnes of magnesium.

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To calculate the mass of magnesium oxide needed, we use the stoichiometry of the reaction. According to the balanced chemical equation:

ightarrow 2 Mg(g)$$ Since the relative atomic mass (Aᵣ) of Mg is 24, we can derive the mass of MgO needed. 1.2 tonnes of Mg = 1200 kg. 2 mol of MgO produces 2 mol of Mg, hence: $$ ext{Mass of MgO} = rac{1.2 ext{ tonnes}}{2 ext{ moles}} imes 2 imes 40 ext{ (molar mass of MgO)} = 1.2 imes 40 ext{ (to convert tonnes to kg)} = 40 kg$$.

Step 7

Calculate the percentage yield.

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Answer

To calculate the percentage yield, we use the formula:

ext{Percentage yield} = rac{ ext{actual yield}}{ ext{theoretical yield}} imes 100

Here, the actual yield is 0.9 tonnes, and the theoretical yield is 1.2 tonnes.

ext{Percentage yield} = rac{0.9}{1.2} imes 100 = 75 ext{%}

Step 8

Give one reason why the calculated yield of magnesium might not be obtained.

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Answer

One possible reason is that there may have been some losses during the reaction process. For instance, reactants could escape during the reaction, or some reactants may react in ways that were not anticipated, producing impurities or by-products.

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