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This question is about displacement reactions - AQA - GCSE Chemistry - Question 6 - 2020 - Paper 1

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This question is about displacement reactions. The displacement reaction between aluminium and iron oxide has a high activation energy. What is meant by 'activ... show full transcript

Worked Solution & Example Answer:This question is about displacement reactions - AQA - GCSE Chemistry - Question 6 - 2020 - Paper 1

Step 1

What is meant by 'activation energy'?

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Answer

Activation energy is the minimum energy required for particles to react. It is the energy needed to break the bonds of the reactants and allow the reaction to proceed.

Step 2

Show that aluminium is the limiting reactant.

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Answer

To determine the limiting reactant, we first calculate the moles of each reactant.

  1. Calculate Molar Mass of Iron(III) Oxide (Fe2O3):

    MFe2O3=2imesArFe+3imesArO=2imes56+3imes16=160extg/molM_{Fe2O3} = 2 imes Ar_{Fe} + 3 imes Ar_{O} = 2 imes 56 + 3 imes 16 = 160 ext{ g/mol}

  2. Calculate Moles of Iron(III) Oxide:

    extMolesofFe2O3=3.00extkg160extg/mol=18.75extmoles ext{Moles of Fe2O3} = \frac{3.00 ext{ kg}}{160 ext{ g/mol}} = 18.75 ext{ moles}

  3. Calculate Moles of Aluminium Needed:

    One mole of ext{Fe2O3} requires 2 moles of aluminium. Therefore, for 18.75 moles:

    extMolesofAlneeded=18.75extmolesimes2=37.5extmoles ext{Moles of Al needed} = 18.75 ext{ moles} imes 2 = 37.5 ext{ moles}

  4. Calculate Moles of Aluminium Available:

    extMolesofAl=1.00extkg27extg/mol=37.037extmoles ext{Moles of Al} = \frac{1.00 ext{ kg}}{27 ext{ g/mol}} = 37.037 ext{ moles}

  5. Conclusion: Since 37.5 moles of Al are needed for the reaction and only 37.037 moles are available, aluminium is the limiting reactant.

Step 3

Complete the ionic equation for the reaction.

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Answer

The balanced ionic equation for the reaction of magnesium and zinc sulfate is:

Mg(s)+Zn2+(aq)Mg2+(aq)+Zn(s)Mg(s) + Zn^{2+}(aq) → Mg^{2+}(aq) + Zn(s)

Step 4

Explain why the reaction between magnesium atoms and zinc ions is both oxidation and reduction.

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Answer

In this reaction, magnesium atoms are oxidized because they lose electrons, transforming from neutral magnesium to magnesium ions (Mg2+{Mg^{2+}}). Conversely, the zinc ions (Zn2+{Zn^{2+}}) gain electrons and are reduced to form solid zinc. This simultaneous loss of electrons by magnesium and gain by zinc highlights the concept of oxidation-reduction (redox) reactions.

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