This question is about rates of reaction - AQA - GCSE Chemistry - Question 1 - 2017 - Paper 1
Question 1
This question is about rates of reaction.
The equation for the decomposition of hydrogen peroxide is:
2H₂O₂ (aq) ⇌ 2H₂O (l) + O₂ (g)
Figure 1 shows the apparatus ... show full transcript
Worked Solution & Example Answer:This question is about rates of reaction - AQA - GCSE Chemistry - Question 1 - 2017 - Paper 1
Step 1
Draw a smooth curve of best fit on Figure 2.
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Answer
A smooth curve should be drawn through or close to all the points presented in Figure 2. It should accurately reflect the trend of the data without jumping between points.
Step 2
Give the volume of oxygen produced at 25 seconds.
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Answer
The volume of oxygen produced at 25 seconds is approximately 12 cm³, based on the reading taken from the curve in part (i).
Step 3
After how many seconds does the reaction stop?
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The reaction stops after approximately 45 to 50 seconds, where no additional oxygen is recorded.
Step 4
Explain how the results support this conclusion.
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The graph indicates that the line becomes less steep over time, demonstrating that the production of oxygen gas decreases, suggesting that the reaction slows as reactants are consumed. For example, during the initial 20 seconds, a significant volume of gas is produced, but in the last 20 seconds, the production rate drops significantly, indicating a decrease in the rate of reaction.
Step 5
Calculate the mean rate of reaction during the first 10 seconds.
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The mean rate of reaction can be calculated by taking the total volume of oxygen produced in the first 10 seconds, which is approximately 6 cm³, and dividing it by the time (10 seconds):
Mean rate of reaction=10 s6 cm3=0.6 cm3 per second
Step 6
Give two other control variables.
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The concentration of hydrogen peroxide should be kept constant; for instance, using the same molarity throughout the experiments.
The temperature at which the reaction occurs should also be controlled to ensure consistent reaction conditions.
Step 7
State and explain, in terms of particles and collisions, how a greater concentration affects the rate of the reaction.
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Increasing the concentration of hydrogen peroxide means there are more particles of reactant present in the same volume. This results in a higher frequency of collisions between reacting particles, thereby increasing the likelihood of effective collisions that lead to reaction. More collisions generally lead to a higher rate of reaction.
Step 8
Describe how increasing the amount of catalyst affects the results in Figure 2.
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Increasing the amount of catalyst results in a steeper graph or causes the graph to level off earlier. This happens because a catalyst provides an alternative pathway for the reaction with a lower activation energy, thereby increasing the rate at which products are formed without affecting the total volume of gas produced.