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A student investigated the electrolysis of different substances - AQA - GCSE Chemistry - Question 6 - 2018 - Paper 1

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A student investigated the electrolysis of different substances. Figure 6 shows the apparatus. Figure 6 Explain why electrolysis would not take place in the appar... show full transcript

Worked Solution & Example Answer:A student investigated the electrolysis of different substances - AQA - GCSE Chemistry - Question 6 - 2018 - Paper 1

Step 1

Explain why electrolysis would not take place in the apparatus shown in Figure 6.

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Answer

Electrolysis would not take place in the apparatus shown in Figure 6 because solid zinc chloride does not conduct electricity. For electrolysis to occur, the ionic compound must either be in a molten state or dissolved in water, allowing ions to move freely.

Step 2

Explain why graphite conducts electricity.

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Answer

Graphite conducts electricity due to its structure and bonding. Each carbon atom in graphite forms three covalent bonds with other carbon atoms, leaving one electron free (delocalized). These delocalized electrons can move freely through the structure, allowing graphite to conduct electricity.

Step 3

How should the apparatus be changed?

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Answer

The apparatus should be changed by using measuring cylinders instead of test tubes, as test tubes cannot measure volume accurately due to their lack of graduations.

Step 4

Describe the trends shown in the results.

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Answer

The trends in Figure 8 indicate that the volume of hydrogen gas collected is directly proportional to the time, suggesting that hydrogen is produced at a constant rate. Up to 8 minutes, chlorine gas is collected at an increasing rate, but after this point, the rate of chlorine collection becomes constant at a similar rate as hydrogen.

Step 5

Suggest one reason for the difference in volume of each gas.

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Answer

One reason for the difference in volume of each gas could be that chlorine is produced at a different rate or that chlorine reacts with water, leading to a difference in the volume collected.

Step 6

Calculate the amount in moles of chlorine collected after 20 minutes.

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Answer

From Figure 8, assume the volume of chlorine collected after 20 minutes is 6.6 cm³. To convert this to moles, use the formula:

moles=volume (dm³)24\text{moles} = \frac{\text{volume (dm³)}}{24}

First, convert 6.6 cm³ to dm³:

6.6cm3=0.0066dm36.6\, \text{cm}^3 = 0.0066\, \text{dm}^3

Now, substituting into the formula:

moles=0.006624=2.75×104 mol\text{moles} = \frac{0.0066}{24} = 2.75 \times 10^{-4} \text{ mol}

Thus, the amount in moles of chlorine collected after 20 minutes is approximately 2.75×104 mol2.75 \times 10^{-4} \text{ mol}.

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