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4 (a) Copper carbonate reacts with dilute nitric acid - Edexcel - GCSE Chemistry Combined Science - Question 4 - 2021 - Paper 1

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4 (a) Copper carbonate reacts with dilute nitric acid. (i) During the reaction the copper carbonate powder completely disappears. State what can be deduced about th... show full transcript

Worked Solution & Example Answer:4 (a) Copper carbonate reacts with dilute nitric acid - Edexcel - GCSE Chemistry Combined Science - Question 4 - 2021 - Paper 1

Step 1

During the reaction the copper carbonate powder completely disappears. State what can be deduced about the amount of acid used.

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Answer

If the copper carbonate powder completely disappears, it indicates that there was an excess of dilute nitric acid used in the reaction. This suggests that all the copper carbonate was reacted, meaning that the acid fully reacted with the carbonate and that not all of the acid was consumed.

Step 2

During the reaction, the pH of the mixture changed from 2 to 6. By what factor has the concentration of the hydrogen ions in the mixture changed?

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Answer

When the pH changes from 2 to 6, it indicates a decrease in the concentration of hydrogen ions. The relationship between pH and hydrogen ion concentration is given by the formula:

[H+]=10pH[H^+] = 10^{-pH}

Thus, for pH 2, the concentration is: [H+]2=102=0.01extM[H^+]_2 = 10^{-2} = 0.01 ext{ M}

And for pH 6, we have: [H+]6=106=0.000001extM[H^+]_6 = 10^{-6} = 0.000001 ext{ M}

To find the factor change:

ext{Factor} = rac{[H^+]_2}{[H^+]_6} = rac{0.01}{0.000001} = 10000

Thus, the correct answer is A x 10000.

Step 3

Using different reactants, a solution of copper sulfate was prepared. Describe what should be done to obtain copper sulfate crystals from this copper sulfate solution.

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Answer

To obtain copper sulfate crystals from a copper sulfate solution, follow these steps:

  1. Evaporation: Heat the solution gently to evaporate some of the water. This will increase the concentration of the copper sulfate in the solution.

  2. Cooling: Allow the concentrated solution to cool slowly. As the solution cools, the solubility of copper sulfate decreases, causing it to crystallize out of the solution.

  3. Separation: Once crystals have formed, filter the solution to separate the crystals from the liquid.

  4. Drying: Finally, place the filtered crystals on a filter paper or drying surface to remove any remaining moisture.

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