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a) Figure 5 shows the structure of a molecule of compound S - Edexcel - GCSE Chemistry Combined Science - Question 6 - 2023 - Paper 1

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a) Figure 5 shows the structure of a molecule of compound S. (i) Use Figure 5 to deduce the empirical formula of compound S. (ii) The melting points of three sam... show full transcript

Worked Solution & Example Answer:a) Figure 5 shows the structure of a molecule of compound S - Edexcel - GCSE Chemistry Combined Science - Question 6 - 2023 - Paper 1

Step 1

Use Figure 5 to deduce the empirical formula of compound S.

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Answer

To deduce the empirical formula, count the number of each type of atom present in compound S. From Figure 5, it is observed that:

  • Carbon (C): 6
  • Hydrogen (H): 12
  • Oxygen (O): 1

The simplest ratio of these atoms is C6H12O. Therefore, the empirical formula is C2H4O.

Step 2

State whether each of these samples, A, B and C, is pure or impure and justify your answers using the information in Figure 6.

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Answer

Sample A (160-164 °C), Sample B (166 °C), and Sample C (163-165 °C).

  • Sample A: Impure, as the melting point range indicates that it is not a single pure substance but a mixture.
  • Sample B: Pure, as it has a sharp melting point at 166 °C, indicating it is likely a single pure substance.
  • Sample C: Impure, due to the indicated melting point range, suggesting it is a mixture.

Step 3

Calculate the distance the spot of compound S moves if the solvent front has moved by 2.4 cm.

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Answer

The formula for calculating the distance moved by the spot is:

extDistancemovedbyspot=RfimesextDistancemovedbysolventfront ext{Distance moved by spot} = R_f imes ext{Distance moved by solvent front}

Substituting the values: extDistancemovedbyspot=0.22imes2.4extcm=0.528extcm ext{Distance moved by spot} = 0.22 imes 2.4 ext{ cm} = 0.528 ext{ cm}

Thus, the distance is 0.53 cm.

Step 4

Explain this difference in boiling points in terms of the structure and bonding of sodium chloride and water and how this difference is used to choose a method to separate sodium chloride solution into pure, dry sodium chloride and pure water.

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Answer

Sodium chloride has a high boiling point of 1465 °C because it consists of strong ionic bonds between sodium and chloride ions, requiring a significant amount of energy to break these bonds.

Water, having a boiling point of 100 °C, is held together by weaker hydrogen bonds between water molecules.

The difference in boiling points allows for a separation technique, such as evaporation. When saltwater is heated, water will evaporate at 100 °C, leaving the solid sodium chloride behind, effectively separating the two substances.

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