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Butene reacts with steam to produce butanol - Edexcel - GCSE Chemistry Combined Science - Question 5 - 2016 - Paper 1

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Butene reacts with steam to produce butanol. C₄H₈ + H₂O → C₄H₉OH (i) Calculate the maximum mass of butanol, C₄H₉OH, that can be produced when 1.4 kg of butene, C₄H... show full transcript

Worked Solution & Example Answer:Butene reacts with steam to produce butanol - Edexcel - GCSE Chemistry Combined Science - Question 5 - 2016 - Paper 1

Step 1

Calculate the maximum mass of butanol, C₄H₉OH, that can be produced when 1.4 kg of butene, C₄H₈, reacts with excess steam.

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Answer

  1. First, we should find the number of moles of butene, C₄H₈:

    Number of moles=massmolar mass=1400g56g/mol=25mol\text{Number of moles} = \frac{\text{mass}}{\text{molar mass}} = \frac{1400\,g}{56\,g/mol} = 25\,mol

  2. The reaction produces 1 mole of butanol for every mole of butene consumed. This means that 25 moles of butene will produce 25 moles of butanol.

  3. Next, calculate the mass of butanol produced:

    Mass=Number of moles×Molar mass of butanol\text{Mass} = \text{Number of moles} \times \text{Molar mass of butanol}

    The molar mass of butanol (C₄H₉OH):

    • Carbon: 4 × 12 = 48

    • Hydrogen: 10 × 1 = 10

    • Oxygen: 1 × 16 = 16

    Molar mass of butanol=48+10+16=74g/mol\text{Molar mass of butanol} = 48 + 10 + 16 = 74\,g/mol

  4. Then, substituting the values:

    Mass of butanol=25mol×74g/mol=1850g\text{Mass of butanol} = 25\,mol \times 74\,g/mol = 1850\,g

    Mass of butanol=1.85kg\text{Mass of butanol} = 1.85\,kg

Step 2

What type of reaction takes place between butene and steam?

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Answer

The reaction that occurs between butene and steam is a dehydration reaction. This can be concluded from the following options:

  • A: addition – NOT correct, since this does not accurately describe the formation of butanol.
  • B: dehydration – CORRECT, as steam reacts with butene under specific conditions to create an alcohol.
  • C: neutralisation – NOT applicable, since no acid-base reaction is involved.
  • D: substitution – INCORRECT, as it does not involve substituting one functional group for another.

Step 3

Using the results, comment on the structures of the hydrocarbons X, Y and Z.

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Answer

For the results obtained from the bromine water tests:

  • Hydrocarbon X turns the orange bromine water colourless, indicating it could be an alkene or an unsaturated compound, as it reacts with bromine.
  • Hydrocarbon Y also turns the bromine water colourless, suggesting it has similar unsaturation or reactivity as hydrocarbon X.
  • Hydrocarbon Z does not react with bromine water and therefore maintains the orange colour, indicating that it is likely a saturated hydrocarbon, such as an alkane, which does not undergo reaction with bromine.

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