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The rate of reaction between magnesium ribbon and dilute hydrochloric acid at room temperature is investigated - Edexcel - GCSE Chemistry Combined Science - Question 6 - 2018 - Paper 1

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The rate of reaction between magnesium ribbon and dilute hydrochloric acid at room temperature is investigated. The apparatus used is shown in Figure 6. The volume... show full transcript

Worked Solution & Example Answer:The rate of reaction between magnesium ribbon and dilute hydrochloric acid at room temperature is investigated - Edexcel - GCSE Chemistry Combined Science - Question 6 - 2018 - Paper 1

Step 1

State a change that can be made to the apparatus in Figure 6 to measure the volumes of gas more accurately.

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Answer

A gas syringe or a burette can be used instead of the measuring cylinder to allow for more precise measurement of the gas volume.

Step 2

Calculate the rate of reaction at this point.

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Answer

To calculate the rate of reaction at the tangent, determine the gradient of the tangent line drawn on the graph at the specified point. The rate of reaction is calculated as:

Rate of reaction=Change in Volume of GasChange in Time\text{Rate of reaction} = \frac{\text{Change in Volume of Gas}}{\text{Change in Time}}

Step 3

On the graph in Figure 7, draw the line you would expect to obtain if the magnesium ribbon in this experiment was replaced with an equal mass of powdered magnesium. All other conditions are kept the same.

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The expected line would demonstrate a steeper increase than that of the magnesium ribbon, indicating a faster rate of reaction due to the greater surface area of the powdered magnesium.

Step 4

Calculate the number of moles of magnesium, Mg, in the 0.1 g sample of magnesium ribbon.

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To find the number of moles:

Number of moles=massmolar mass\text{Number of moles} = \frac{\text{mass}}{\text{molar mass}}

Using the given data:

Number of moles=0.1 g24 g/mol=0.00417 mol\text{Number of moles} = \frac{0.1 \text{ g}}{24 \text{ g/mol}} = 0.00417 \text{ mol}

Step 5

Use the equation to show that, in this experiment, the magnesium is in excess.

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Answer

The balanced chemical equation is:

Mg+2HClMgCl2+H2\text{Mg} + 2\text{HCl} → \text{MgCl}_2 + \text{H}_2

From the reaction, one mole of magnesium reacts with two moles of HCl. Since we have 0.5 mol of HCl, it will require:

0.5 mol HCl×1 mol Mg2 mol HCl=0.25 mol Mg0.5 \text{ mol HCl} \times \frac{1 \text{ mol Mg}}{2 \text{ mol HCl}} = 0.25 \text{ mol Mg}

Since we only have 0.5 mol of Mg available, magnesium is indeed in excess.

Step 6

Explain, in terms of the behaviour of particles, the effect of changing temperature.

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Answer

As temperature increases, the kinetic energy of the particles increases. This results in more frequent and effective collisions between the reactant particles, leading to an increased rate of reaction.

Step 7

Explain, in terms of the behaviour of particles, the effect of changing concentration of A in solution on the rate of the reaction.

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Answer

Increasing the concentration of A increases the number of particles in a given volume. This leads to a higher likelihood of collisions between the reactant particles, therefore increasing the rate of reaction.

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