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10 (a) A sample of potassium carbonate is contaminated with a small amount of sodium carbonate - Edexcel - GCSE Chemistry - Question 10 - 2019 - Paper 1

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10 (a) A sample of potassium carbonate is contaminated with a small amount of sodium carbonate. When a flame test is carried out on the sample, a bright yellow flame... show full transcript

Worked Solution & Example Answer:10 (a) A sample of potassium carbonate is contaminated with a small amount of sodium carbonate - Edexcel - GCSE Chemistry - Question 10 - 2019 - Paper 1

Step 1

Describe how you could show that potassium and sodium ions are present in this sample.

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Answer

To confirm the presence of potassium and sodium ions in the sample, you can perform a flame test.

  1. Flame Test Procedure: Take a small amount of the solid sample and place it on a clean platinum wire or a wooden splint.
  2. Observation: Hold the splint in a Bunsen burner flame.
  3. Expected Results: If potassium ions are present, a lilac or purple flame will be produced, confirming their presence. Sodium ions will produce a bright yellow flame, which is typical for sodium when it is present in the sample.
  4. Comparison: Use known reference samples for potassium and sodium salts to compare the flame colors for accuracy.

Step 2

Write the ionic equation for this reaction.

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Answer

The ionic equation for the reaction between hydrochloric acid and sodium carbonate can be derived as follows:

  1. Identify the reactants and products:

    • The reactants are hydrochloric acid (HCl) and sodium carbonate (Na2CO3).
    • The products are sodium chloride (NaCl), carbon dioxide (CO2), and water (H2O).
  2. Write the complete ionic equation:

    2H+(aq)+CO32(aq)2Na+(aq)+2Cl(aq)+CO2(g)+H2O(l)2H^+(aq) + CO_3^{2-}(aq) \rightarrow 2Na^+(aq) + 2Cl^-(aq) + CO_2(g) + H_2O(l)

  3. Cancel the spectator ions: Sodium ions (Na+) and chloride ions (Cl-) do not participate in the reaction. Therefore, the net ionic equation is:

2H+(aq)+CO32(aq)CO2(g)+H2O(l)2H^+(aq) + CO_3^{2-}(aq) \rightarrow CO_2(g) + H_2O(l)

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