1 (a) The ions in sodium chloride solution are
sodium ions, Na⁺
chloride ions, Cl⁻
hydrogen ions, H⁺
hydroxide ions, OH⁻
Sodium chloride solution is electrolysed using a direct electric current - Edexcel - GCSE Chemistry - Question 1 - 2013 - Paper 1
Question 1
1 (a) The ions in sodium chloride solution are
sodium ions, Na⁺
chloride ions, Cl⁻
hydrogen ions, H⁺
hydroxide ions, OH⁻
Sodium chloride solution is el... show full transcript
Worked Solution & Example Answer:1 (a) The ions in sodium chloride solution are
sodium ions, Na⁺
chloride ions, Cl⁻
hydrogen ions, H⁺
hydroxide ions, OH⁻
Sodium chloride solution is electrolysed using a direct electric current - Edexcel - GCSE Chemistry - Question 1 - 2013 - Paper 1
Step 1
Which of these ions will be attracted to the cathode during the electrolysis of sodium chloride solution?
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Answer
The ions that will be attracted to the cathode during the electrolysis of sodium chloride solution are B) H⁺ and Na⁺ ions. This is because cations, or positively charged ions, migrate towards the cathode, where reduction occurs.
Step 2
Explain how the half-equation shows that chloride ions are oxidised.
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Answer
The half-equation for the production of chlorine, 2Cl⁻ → Cl₂ + 2e⁻, indicates oxidation as it illustrates the loss of electrons by chloride ions. In this process, two chloride ions each lose one electron, resulting in the formation of a chlorine molecule.
Step 3
Suggest why the solution remaining at the end of the electrolysis is alkaline.
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Answer
The solution remaining at the end of the electrolysis is alkaline because hydroxide ions (OH⁻) are produced when water is also electrolysed. This increase in hydroxide ions results in a basic (alkaline) solution.
Step 4
State what change you would make to the electrolyte to obtain metallic sodium.
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Answer
To obtain metallic sodium from the electrolysis of sodium chloride solution, I would change the electrolyte to molten sodium chloride instead of the aqueous solution. This would allow sodium ions to be reduced at the cathode to form metallic sodium.
Step 5
Explain how the oxygen is formed from ions in the solution.
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Answer
Oxygen is formed at the anode during the electrolysis of copper sulfate solution when water molecules lose electrons. The hydroxide ions (OH⁻) in the solution lose electrons, resulting in the formation of oxygen gas and water.
Step 6
Calculate the number of moles of copper, Cu, produced in this experiment.
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Answer
To calculate the number of moles of copper produced, we use the formula:
Number of moles =
[ \frac{\text{mass}}{\text{molar mass}} = \frac{1.27 , ext{g}}{63.5 , \text{g/mol}} = 0.02 , \text{mol} ]
Therefore, the number of moles of copper produced is 0.02 mol.